The performance of Nafion®424 in the membrane electrolysis of borax solution

被引：9
|
作者：
Turan, Abdullah Zahid [1 ]
Elbeyli, Iffet Yakar [1 ]
Bahar, Tahsin [1 ]
Kalafatoglu, I. Ersan [2 ]
机构：
[1] TUBITAK Marmara Res Ctr, Inst Chem, TR-41470 Gebze, Kocaeli, Turkey
[2] Marmara Univ, Fac Engn, Dept Met & Mat Engn, TR-34722 Istanbul, Turkey
来源：
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2012年 / 18卷 / 03期
关键词：
Membrane electrolysis; Borax; Boric acid; Sodium hydroxide; Nafion; (R); 424; SYSTEM; WATER;
D O I：
10.1016/j.jiec.2011.12.014
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The aim of the study was to investigate the performance of a monolayer cation exchange membrane (Nafion (R) 424) in the membrane electrolysis of aqueous borax solution. Membrane cell was basically composed of a hydrogen evolving cathode, oxygen evolving anode and Nafion (R) 424. Boric acid solution, sodium hydroxide solution, oxygen and hydrogen gases were produced by continuous electrolysis process. The effects of different catholyte concentrations (10, 20, 30 and 35% NaOH) on the current efficiency were investigated. The electrical power consumption per ton for the production of sodium hydroxide (100%) and boric acid were calculated and the qualities of boric acid products were determined. (C) 2012 The Korean Society of industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：1102 / 1106
页数：5
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