Sol-Gel Synthesis of Inorganic Mesostructured Composite Photocatalyst for Water Purification: An Insight Into the Synthesis Fundamentals, Reaction, and Binding Mechanisms

被引:9
作者
Chong, Meng Nan [1 ,2 ,3 ]
Jin, Bo [2 ,3 ,4 ]
机构
[1] CSIRO Land & Water, Ecosci Precinct, Dutton Pk, Qld 4102, Australia
[2] Univ Adelaide, Sch Chem Engn, Adelaide, SA, Australia
[3] Univ Adelaide, Sch Earth & Environm Sci, Adelaide, SA, Australia
[4] SA Water Corp, Australian Water Qual Ctr, Adelaide, SA, Australia
基金
澳大利亚研究理事会;
关键词
functional composites; nanomaterials; photocatalysts; sol-gel methods; water purification; ADVANCED OXIDATION PROCESSES; DEGRADATION; TIO2;
D O I
10.1080/15533174.2011.609231
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The paper discusses the sol-gel synthesis of an inorganic mesostructured composite photocatalyst for application in water purification. The fundamentals for each synthesis step on the final Ti-content, anatase-to-rutile composition, bonding structure and mechanism to kaolinite, shape, surface area, and size control were described. In addition, various advanced microscopic techniques were used to characterize and validate the physical and chemical properties of the composite photocatalyst. A hypothetical schematic for the fabrication of mesostructured composite photocatalyst was also presented to better illustrate the overall reaction and binding mechanism. The photocatalytic degradation of an aqueous dye solution was also investigated.
引用
收藏
页码:68 / 75
页数:8
相关论文
共 17 条
[1]  
Barrer R.M., 1978, Zeolites and Clay Minerals As Sorbents And Molecular Sieves
[2]   Implications of heat treatment on the properties of a magnetic iron oxide-titanium dioxide photocatalyst [J].
Beydoun, D ;
Amal, R .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2002, 94 (01) :71-81
[3]   Recent developments in photocatalytic water treatment technology: A review [J].
Chong, Meng Nan ;
Jin, Bo ;
Chow, Christopher W. K. ;
Saint, Chris .
WATER RESEARCH, 2010, 44 (10) :2997-3027
[4]   Synthesis and characterisation of novel titania impregnated kaolinite nano-photocatalyst [J].
Chong, Meng Nan ;
Vimonses, Vipasiri ;
Lei, Shaomin ;
Jin, Bo ;
Chow, Chris ;
Saint, Chris .
MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 117 (1-2) :233-242
[5]   Comparison of different advanced oxidation processes for phenol degradation [J].
Esplugas, S ;
Giménez, J ;
Contreras, S ;
Pascual, E ;
Rodríguez, M .
WATER RESEARCH, 2002, 36 (04) :1034-1042
[6]  
Gates BC, 2004, ADV CATALYSIS
[7]   Effects of aging on the phase transformation and sintering properties of TiO2 gels [J].
Hsiang, HI ;
Lin, SC .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2004, 380 (1-2) :67-72
[8]   Antimicrobial nanomaterials for water disinfection and microbial control: Potential applications and implications [J].
Li, Qilin ;
Mahendra, Shaily ;
Lyon, Delina Y. ;
Brunet, Lena ;
Liga, Michael V. ;
Li, Dong ;
Alvarez, Pedro J. J. .
WATER RESEARCH, 2008, 42 (18) :4591-4602
[9]  
Limmer S.J., 2006, NANOWIRES NANOBELTS, V2, P93
[10]   Solar photocatalytic degradation of dyes:: high activity of combustion synthesized nano TiO2 [J].
Nagaveni, K ;
Sivalingam, G ;
Hedge, MS ;
Madras, G .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 48 (02) :83-93