Iodo(phthalocyaninato)vanadium(III)

被引：10

作者：

Ejsmont, K

Kubiak, R

机构：

[1] Univ Opole, Inst Chem, PL-45052 Opole, Poland

[2] Polish Acad Sci, W Trzebiatowski Inst Low Temp & Struct Res, PL-50950 Wroclaw, Poland

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270198008105

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new vanadium phthalocyanine complex with the formula [VI(C32H16N8)], or PcVI (Pc = C32H16N8), has been obtained by the reaction of pure V powder with 1,2-dicyanobenzene under iodine vapour. The V atom is bonded to one apical iodide ligand and four N-isoindole atoms, and has square-pyramidal coordination geometry. The mean V-N-isoindole distance is 1.952 (3) Angstrom. The VI bond has a length of 2.6279 (8) Angstrom and is tilted 1.7 (1)degrees to the normal of the plane formed by the four N-isoindole atoms. The phthalocyaninato ligand is saucer-shaped.

引用

页码：1844 / 1846

页数：3

共 6 条

[1] *KUM, 1997, KUM DIFFR SOFTW VERS
[2] CRYSTAL AND MOLECULAR STRUCTURE OF VANADYLDEOXOPHYLLO-ERYTHROETIOPORPHYRIN-1,2-DICHLOROETHANE SOLVATE - AN ANALOGUE OF CHLOROPHYLL
PETTERSEN, RC
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1969, B 25 : 2527 - +
[3] Redox chemistry associated with the complexation of vanadium(V) and tungsten(VI) by meso-octaethylporphyrinogen: Formation and cleavage of cyclopropane units functioning as shuttles of two electrons
Piarulli, U
Solari, E
Floriani, C
ChiesiVilla, A
Rizzoli, C
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (15) : 3634 - 3642
[4] Sheldrick G. M., 1990, SHELXTL
[5] SHELDRICK GM, 1997, SHELX97 PROGRAM SOLU
[6] CRYSTAL-STRUCTURE OF VANADYL PHTHALOCYANINE, PHASE-II
ZIOLO, RF
GRIFFITHS, CH
TROUP, JM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (11): : 2300 - 2302

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