Photoconductive Cathode Inter layer for Highly Efficient Inverted Polymer Solar Cells

被引：237

作者：

Nian, Li ^{[1
]}

Zhang, Wenqiang ^{[1
]}

Zhu, Na ^{[1
]}

Liu, Linlin ^{[1
]}

Xie, Zengqi ^{[1
]}

Wu, Hongbin ^{[1
]}

Wuerthner, Frank ^{[2
,3
]}

Ma, Yuguang ^{[1
]}

机构：

[1] S China Univ Technol, State Key Lab Luminescent Mat & Devices, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China

[2] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

[3] Univ Wurzburg, Ctr Nanosyst Chem, D-97074 Wurzburg, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 22期

关键词：

ELECTRON-TRANSPORT LAYER; OPEN-CIRCUIT VOLTAGE; LOW-BANDGAP POLYMER; HIGH-PERFORMANCE; PHOTOVOLTAIC CELLS; SINGLE JUNCTION; TANDEM POLYMER; NANOPARTICLES; DESIGN;

D O I：

10.1021/jacs.5b02168

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly photoconductive cathode inter, layer was achieved by doping a 1 wt % light absorber, such as perylene bisimide, into a ZnO thin film, which absorbs a very small amount of light but shows highly increased conductivity of 4.50 x 10(-3) S/m under sunlight. Photovoltaic devices based on this kind of photoactive cathode interlayer exhibit significantly improved device performance, which is rather insensitive to the thickness of the cathode interlayer over a broad range. Moreover, a power conversion efficiency as high as 10.5% was obtained by incorporation of our photoconductive cathode interlayer with the PTB7-Th:PC71BM active layer, which is one of the best results for single-junction polymer solar cells:

引用

页码：6995 / 6998

页数：4

共 31 条

[31] A Universal Method to Produce Low-Work Function Electrodes for Organic Electronics [J].

Zhou, Yinhua ;

Fuentes-Hernandez, Canek ;

Shim, Jaewon ;

Meyer, Jens ;

Giordano, Anthony J. ;

Li, Hong ;

Winget, Paul ;

Papadopoulos, Theodoros ;

Cheun, Hyeunseok ;

Kim, Jungbae ;

Fenoll, Mathieu ;

Dindar, Amir ;

Haske, Wojciech ;

Najafabadi, Ehsan ;

Khan, Talha M. ;

Sojoudi, Hossein ;

Barlow, Stephen ;

Graham, Samuel ;

Bredas, Jean-Luc ;

Marder, Seth R. ;

Kahn, Antoine ;

Kippelen, Bernard .

SCIENCE, 2012, 336 (6079) :327-332

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