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Application of water barrier layers in a proton exchange membrane fuel cell for improved water management at low humidity conditions
被引:28
作者:
Blanco, Mauricio
[1
,2
,3
]
Wilkinson, David P.
[1
,2
,3
]
Wang, Haijiang
[3
]
机构:
[1] Univ British Columbia, Dept Chem & Biol Engn, Vancouver, BC V6T 1Z3, Canada
[2] Univ British Columbia, Clean Energy Res Ctr, Vancouver, BC V6T 1Z3, Canada
[3] Natl Res Council Canada, Inst Fuel Cell Innovat, Vancouver, BC V6T 1W5, Canada
基金:
加拿大自然科学与工程研究理事会;
关键词:
Water management;
Proton exchange membrane fuel cell;
Dry condition;
Durability;
Gas diffusion layer;
Stainless steel perforated sheets;
POLYMER ELECTROLYTE MEMBRANES;
TRANSPORT-PROPERTIES;
MATHEMATICAL-MODEL;
METHANOL TRANSPORT;
PRESSURE-DROP;
DIFFUSION;
HUMIDIFICATION;
DESIGN;
VISUALIZATION;
OPERATION;
D O I:
10.1016/j.ijhydene.2010.12.108
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
This study discusses the use of an additional layer in the cathode side of a proton exchange membrane fuel cell (PEMFC) for improved water management at dry conditions. The performance of fuel cells deteriorates significantly when low to no gas humidification is used. This study demonstrates that adding a non-porous material with perforations, such as stainless steel, between the cathode flow field plate and the gas diffusion layer (GDL) improves the water saturation in the cathode GDL and catalyst layer, increases the water content in the anode, and keeps the membrane hydrated. The slight voltage drop in the performance as a result of transport limitations is justifiable since the overall durability of the cell at these extreme conditions is enhanced. The results show that the perforated layer(s) enhances the operational life of the PEMFC under completely dry conditions. These extreme conditions (dry gases without humidification, 90 kPa, 75 degrees C) were used to accelerate the failure modes in the fuel cells. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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页码:3635 / 3648
页数:14
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