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Significant improvement of the oxygen permeation flux of tubular Ba0.5Sr0.5Co0.8Fe0.2O3-δ membranes covered by a thin La0.6Sr0.4Ti0.3Fe0.7O3-δ layer
被引:16
|作者:
Kim, Jong Pyo
[2
]
Park, Jung Hoon
[1
]
Magnone, Edoardo
[1
]
Lee, Yongtaek
[2
]
机构:
[1] Korea Inst Energy Res, Greenhouse Gas Res Ctr, Climate Change Technol Res Div, Taejon 305343, South Korea
[2] Chungnam Natl Univ, Dept Chem Engn, Taejon 305764, South Korea
关键词:
Ceramics;
Perovskite;
Membrane;
Thin films;
Oxygen permeation;
TRANSPORT-PROPERTIES;
STABILITY;
TI;
D O I:
10.1016/j.matlet.2011.04.031
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
We present a new method to improve the oxygen flux properties and stability of Ba0.5Sr0.5Co0.8Fe0.2O3-delta tube membrane using a thin layer of La0.6Sr0.4Ti0.3Fe0.7O3-delta as protective coatings. The first relevant result is that the La0.6Sr0.4Ti0.3Fe0.7O3-delta protective layer had an extraordinary positive effect on improving the oxygen permeation flux of the tubular Ba0.5Sr0.5Co0.8Fe0.2O3-delta membranes. La0.6Sr0.4Ti0.3Fe0.7O3-delta-coated Ba0.5Sr0.5Co0.8Fe0.2O3-delta tubular membrane showed the highest oxygen permeability with the flux reaching similar to 3 ml cm(-2)min(-1) (oxygen purity >99%) at 950 degrees C in static atmospheric pressure through a 1.0 mm thick membrane. (C) 2011 Elsevier B.V. All rights reserved.
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页码:2168 / 2170
页数:3
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