Significant improvement of the oxygen permeation flux of tubular Ba0.5Sr0.5Co0.8Fe0.2O3-δ membranes covered by a thin La0.6Sr0.4Ti0.3Fe0.7O3-δ layer

被引:16
|
作者
Kim, Jong Pyo [2 ]
Park, Jung Hoon [1 ]
Magnone, Edoardo [1 ]
Lee, Yongtaek [2 ]
机构
[1] Korea Inst Energy Res, Greenhouse Gas Res Ctr, Climate Change Technol Res Div, Taejon 305343, South Korea
[2] Chungnam Natl Univ, Dept Chem Engn, Taejon 305764, South Korea
关键词
Ceramics; Perovskite; Membrane; Thin films; Oxygen permeation; TRANSPORT-PROPERTIES; STABILITY; TI;
D O I
10.1016/j.matlet.2011.04.031
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present a new method to improve the oxygen flux properties and stability of Ba0.5Sr0.5Co0.8Fe0.2O3-delta tube membrane using a thin layer of La0.6Sr0.4Ti0.3Fe0.7O3-delta as protective coatings. The first relevant result is that the La0.6Sr0.4Ti0.3Fe0.7O3-delta protective layer had an extraordinary positive effect on improving the oxygen permeation flux of the tubular Ba0.5Sr0.5Co0.8Fe0.2O3-delta membranes. La0.6Sr0.4Ti0.3Fe0.7O3-delta-coated Ba0.5Sr0.5Co0.8Fe0.2O3-delta tubular membrane showed the highest oxygen permeability with the flux reaching similar to 3 ml cm(-2)min(-1) (oxygen purity >99%) at 950 degrees C in static atmospheric pressure through a 1.0 mm thick membrane. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:2168 / 2170
页数:3
相关论文
共 50 条
  • [31] Oxygen exchange-limited transport and surface activation of Ba0.5Sr0.5Co0.8Fe0.2O3-δ capillary membranes
    Kovalevsky, A.
    Buysse, C.
    Snijkers, F.
    Buekenhoudt, A.
    Luyten, J.
    Kretzschmar, J.
    Lenaerts, S.
    JOURNAL OF MEMBRANE SCIENCE, 2011, 368 (1-2) : 223 - 232
  • [32] Influence of sintering conditions on microstructure and oxygen permeation of Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) oxygen transport membranes
    Baumann, S.
    Schulze-Kueppers, F.
    Roitsch, S.
    Betz, M.
    Zwick, M.
    Pfaff, E. M.
    Meulenberg, W. A.
    Mayer, J.
    Stoever, D.
    JOURNAL OF MEMBRANE SCIENCE, 2010, 359 (1-2) : 102 - 109
  • [33] Fabrication and Permeation Properties of Tubular Ba0.5Sr0.5Co0.8Fe0.2O3-delta Membranes for Oxygen Separation
    Kim, Jong Pyo
    Son, Sou Hwan
    Park, Jung Hoon
    Lee, Yongtaek
    KOREAN CHEMICAL ENGINEERING RESEARCH, 2011, 49 (06): : 804 - 809
  • [34] Diffusion of La and Mn in Ba0.5Sr0.5Co0.8Fe0.2O3-δ polycrystalline ceramics
    Harvey, Steven P.
    De Souza, Roger A.
    Martin, Manfred
    ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (02) : 5803 - 5813
  • [35] Effect of surface modification of Ba0.5Sr0.5Co0.8Fe0.2O3-δ membrane for oxygen separation
    Park, Jung Hoon
    Kim, Jong Pyo
    Son, Sou Hwan
    Choi, Soo Hyun
    Baek, Il Hyun
    10TH INTERNATIONAL CONFERENCE ON GREENHOUSE GAS CONTROL TECHNOLOGIES, 2011, 4 : 653 - 658
  • [36] Manufacturing and performance of advanced supported Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) oxygen transport membranes
    Schulze-Kueppers, F.
    Baumann, S.
    Meulenberg, W. A.
    Stoever, D.
    Buchkremer, H. -P.
    JOURNAL OF MEMBRANE SCIENCE, 2013, 433 : 121 - 125
  • [37] Reinvestigation of the Permeation Behaviour of a Ba0.5Sr0.5Co0.8Fe0.2O3-δ Perovskite-type Membrane
    Alaee, Mohammad Ali
    Ghadimi, Ali
    Mohammadi, Toraj
    HIGH TEMPERATURE MATERIALS AND PROCESSES, 2009, 28 (03) : 181 - 190
  • [38] Oxygen permeation study and improvement of Ba0.5Sr0.5Co0.8Fe0.2Ox perovskite ceramic membranes
    Jiang, Qiying
    Nordheden, Karen J.
    Stagg-Williams, Susan M.
    JOURNAL OF MEMBRANE SCIENCE, 2011, 369 (1-2) : 174 - 181
  • [39] Influence of a La0.6Sr0.4CoO3-δ Functional Layer on (Ba0.5Sr0.5)(Co0.8Fe0.2)O3-δ Oxygen Transport Membranes (OTMs)
    Unger, L. -S.
    Meffert, M.
    Wilde, V.
    Stoermer, H.
    Niedrig, C.
    Menesklou, W.
    Wagner, S. F.
    Gerthsen, D.
    Ivers-Tiffee, E.
    IONIC AND MIXED CONDUCTING CERAMICS 10, 2016, 72 (07): : 37 - 45
  • [40] Experimental and modeling studies on Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) tubular membranes for air separation
    Wang, HH
    Wang, R
    Liang, DT
    Yang, WS
    JOURNAL OF MEMBRANE SCIENCE, 2004, 243 (1-2) : 405 - 415