Template synthesis of defect-rich MoS2-based assemblies as electrocatalytic platforms for hydrogen evolution reaction

被引：39
作者：
Kagkoura, Antonia [1 ]
Tzanidis, Iordanis [2 ]
Dracopoulos, Vassilios [3 ]
Tagmatarchis, Nikos [1 ]
Tasis, Dimitrios [2 ,3 ]
机构：
[1] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, 48 Vassileos Constantinou Ave, GR-11635 Athens, Greece
[2] Univ Ioannina, Dept Chem, GR-45110 Ioannina, Greece
[3] FORTH ICEHT, Fdn Res & Technol, Hellas Inst Chem Engn Sci, Stadiou Str,POB 1414, Patras 26504, Greece
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 14期
基金：
欧盟地平线“2020”;
关键词：
ACTIVE EDGE SITES; MOLYBDENUM-DISULFIDE; MOS2; NANOSHEETS; GRAPHENE; H-2; WS2;
D O I：
10.1039/c9cc00051h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Defect-rich MoS2 nanostructures were synthesized in solution by a microwave-assisted process, employing either a sacrificial soft template (CaCO3) or a non-sacrificial hard template (graphene oxide) and the electrocatalytic performance towards the hydrogen evolution reaction was found to be superior for the latter.
引用
收藏
页码：2078 / 2081
页数：4
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  • [1] The Effect of Thermal Reduction on the Water Vapor Permeation in Graphene Oxide Membranes
    Andrikopoulos, Konstantinos S.
    Bounos, Giannis
    Tasis, Dimitrios
    Sygellou, Lamprini
    Drakopoulos, Vassilios
    Voyiatzis, Georgios A.
    [J]. ADVANCED MATERIALS INTERFACES, 2014, 1 (08):
  • [2] Balancing the Hydrogen Evolution Reaction, Surface Energetics, and Stability of Metallic MoS2 Nanosheets via Covalent Functionalization
    Benson, Eric E.
    Zhang, Hanyu
    Schuman, Samuel A.
    Nanayakkara, Sanjini U.
    Bronstein, Noah D.
    Ferrere, Suzanne
    Blackburn, Jeffrey L.
    Miller, Elisa M.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (01) : 441 - 450
  • [3] Electronic Interactions in Illuminated Carbon Dot/MoS2 Ensembles and Electrocatalytic Activity towards Hydrogen Evolution
    Canton-Vitoria, Ruben
    Vallan, Lorenzo
    Urriolabeitia, Esteban
    Benito, Ana M.
    Maser, Wolfgang K.
    Tagmatarchis, Nikos
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (41) : 10468 - 10474
  • [4] Vertically Aligned Interlayer Expanded MoS2 Nanosheets on a Carbon Support for Hydrogen Evolution Electrocatalysis
    Chatti, Manjunath
    Gengenbach, Thomas
    King, Russell
    Spiccia, Leone
    Simonov, Alexandr N.
    [J]. CHEMISTRY OF MATERIALS, 2017, 29 (07) : 3092 - 3099
  • [5] Ultrathin WS2 Nanoflakes as a High-Performance Electrocatalyst for the Hydrogen Evolution Reaction
    Cheng, Liang
    Huang, Wenjing
    Gong, Qiufang
    Liu, Changhai
    Liu, Zhuang
    Li, Yanguang
    Dai, Hongjie
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (30) : 7860 - 7863
  • [6] Electrochemistry of Nanostructured Layered Transition-Metal Dichalcogenides
    Chia, Xinyi
    Eng, Alex Yong Sheng
    Ambrosi, Adriano
    Tan, Shu Min
    Pumera, Martin
    [J]. CHEMICAL REVIEWS, 2015, 115 (21) : 11941 - 11966
  • [7] Thickness-modulated metal-to-semiconductor transformation in a transition metal dichalcogenide
    Ciarrocchi, Alberto
    Avsar, Ahmet
    Ovchinnikov, Dmitry
    Kis, Andras
    [J]. NATURE COMMUNICATIONS, 2018, 9
  • [8] Interfacial processes involving electrocatalytic evolution and oxidation of H2, and the role of chemisorbed H
    Conway, BE
    Tilak, BV
    [J]. ELECTROCHIMICA ACTA, 2002, 47 (22-23) : 3571 - 3594
  • [9] Photoluminescence from Chemically Exfoliated MoS2
    Eda, Goki
    Yamaguchi, Hisato
    Voiry, Damien
    Fujita, Takeshi
    Chen, Mingwei
    Chhowalla, Manish
    [J]. NANO LETTERS, 2011, 11 (12) : 5111 - 5116
  • [10] Edge-terminated molybdenum disulfide with a 9.4-Å interlayer spacing for electrochemical hydrogen production
    Gao, Min-Rui
    Chan, Maria K. Y.
    Sun, Yugang
    [J]. NATURE COMMUNICATIONS, 2015, 6
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