The first triple-decker complex with the PtMe3 fragment: CpCo(μ-1,3-C3B2Me5)PtMe3

被引：4

作者：

Romanov, Alexander S. ^{[1
]}

Muratov, Dmitry V. ^{[1
]}

Petrovskii, Pavel V. ^{[1
]}

Siebert, Walter ^{[2
]}

Kudinov, Alexander R. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

[2] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

MENDELEEV COMMUNICATIONS | 2012年 / 22卷 / 01期

关键词：

ELECTRONIC-STRUCTURE; DENSITY; APPROXIMATION; ENERGY; TERMS; BONDS;

D O I：

10.1016/j.mencom.2012.01.004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mu-diborolyl triple-decker complex CpCo(mu-1,3-C3B2Me5)PtMe3 was prepared by reaction of the sandwich anion [CpCo(1,3-C3B2Me5)](-) with [PtMe3I](4); according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C3B2Me5)](-) and [PtMe3](+) fragments are similar to 64% electrostatic and 36% covalent.

引用

页码：13 / 14

页数：2