Hydrothermal synthesis and crystal structure of coordination polymer [NaMn(pic)3]n

被引：0

作者：

Xu Min ^{[1
]}

Lue Ying-Jie ^{[1
]}

Wang Dong-Yao ^{[1
]}

Dong Wen ^{[1
]}

机构：

[1] Guangzhou Univ, Sch Chem & Chem Engn, Guangzhou 510006, Guangdong, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 24卷 / 05期

关键词：

manganese coordination polymer; picolinic acid; crystal structure; hydrothermal synthesis;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Coordination polymer [NaMn(pic)(3)](n) (1) (picH=picolinic acid) has been synthesized by hydrothermal synthesis and structurally characterized by single crystal structure determination. I crystallizes in the orthorhombic space group Pbca, a=1.251 9(4) nm, b=1.715 8(8) nm, c=1.754 7(7) nm, V=3.769(6) nm(3), M-r=444.24, D-c=1.566, F(000)=1800, R-1=0.024 8 and wR(2)=0-075 1 for I > 2 sigma(I). According to the crystal structure, each Mn(II) ion of 1 is six-coordinated with three oxygen and three nitrogen atoms from three pie anions to form a distorted dodecahedron. Each Na+ ion of 1 is penta-coordinated with two oxygen atoms from a pie anion and three oxygen atoms from three pie anions of diffrent unit to form a distorted tetragnal pyramid. The three-dimensional coordination polymer 1 is connected through Na+ ion. CCDC: 683029.

引用

页码：827 / 830

页数：4

共 12 条

[1] Single-molecule magnets: a molecular approach to nanoscale magnetic materials
Christou, G
[J]. POLYHEDRON, 2005, 24 (16-17) : 2065 - 2075
[2] Decanuclear manganese(III) complexes with the [Mn10O8](14+) core: Structural and magnetochemical characterization of [Mn10O8(O(2)CPh)(6)(chel)(8)] (chel=pic, dbm)
Eppley, HJ
Aubin, SMJ
Streib, WE
Bollinger, JC
Hendrickson, DN
Christou, G
[J]. INORGANIC CHEMISTRY, 1997, 36 (01) : 109 - 115
[3] Synthesis, crystal structure, and magnetic behavior of two dicyanamido-bridged complexes of manganese(II): Effect of weak interaction in carving regular geometry
Ghoshal, D
Ghosh, AK
Ribas, J
Zangrando, E
Mostafa, G
Maji, TK
Chaudhuri, NR
[J]. CRYSTAL GROWTH & DESIGN, 2005, 5 (03) : 941 - 947
[4] Synthesis, structural characterizations and magnetic properties of a series of mono-, di- and polynuclear manganese pyridinecarboxylate compounds
Huang, DG
Wang, WG
Zhang, XF
Chen, CN
Chen, F
Liu, QT
Liao, DZ
Li, LC
Sun, LC
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (07) : 1454 - 1464
[5] CRYSTAL-STRUCTURE AND MAGNETIC-SUSCEPTIBILITY OF THE DINUCLEAR MANGANESE(IV) COMPLEX MN2O2(PIC)4.MECN (PICH = PICOLINIC-ACID)
LIBBY, E
WEBB, RJ
STREIB, WE
FOLTING, K
HUFFMAN, JC
HENDRICKSON, DN
CHRISTOU, G
[J]. INORGANIC CHEMISTRY, 1989, 28 (21) : 4037 - 4040
[6] A homochiral metal-organic porous material for enantioselective separation and catalysis
Seo, JS
Whang, D
Lee, H
Jun, SI
Oh, J
Jeon, YJ
Kim, K
[J]. NATURE, 2000, 404 (6781) : 982 - 986
[7] Shi W, 2003, CHEM J CHINESE U, V24, P516
[8] Synthesis, structure and magnetic properties of the first two-dimensional infinite sheet-like mixed-valence manganese(II,III) complex with bridging salicylate and pyridine-2-carboxylate ligands
Tan, XS
Ma, ZS
Shi, NC
Fu, DG
Chen, J
Tang, WX
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (13): : 2735 - 2738
[9] PREPARATION AND PHYSICAL-PROPERTIES OF TRINUCLEAR OXO-CENTERED MANGANESE COMPLEXES OF THE GENERAL FORMULATION [MN3O(O2CR)6L3]0,+ (R = ME OR PH, L = A NEUTRAL DONOR GROUP) AND THE CRYSTAL-STRUCTURES OF [MN3O(O2CME)6(PYR)3](PYR) AND [MN3O(O2CPH)6(PYR)2(H2O)].0.5MECN
VINCENT, JB
CHANG, HR
FOLTING, K
HUFFMAN, JC
CHRISTOU, G
HENDRICKSON, DN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) : 5703 - 5711
[10] One-dimensional pyrazine bridged M(II)-saccharinato coordination polymers: Synthesis, characterization, crystal structures and thermal studies
Yilmaz, Veysel T.
Senel, Evrim
Kazak, Canan
[J]. POLYHEDRON, 2007, 26 (13) : 3199 - 3204

← 1 2 →