Hydrogen Peroxide Generation Using Polyaniline/Transition Metal Nanohybrid Electrodes

被引：3

作者：

Isaji, Tadayuki ^{[1
,2
]}

Abe, Masashi ^{[2
]}

Amaya, Toru ^{[1
]}

Hirao, Toshikazu ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Nissan Chem Ind Co Ltd, Sodegaura, Chiba 111, Japan

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2015年 / 25卷 / 04期

关键词：

Polyaniline; Transition metal; Nanohybrid; Hydrogen peroxide; SULFONIC ACID)/GOLD NANOPARTICLES; CONJUGATED COMPLEX-SYSTEMS; OXYGEN REDUCTION; AQUEOUS-MEDIA; CATALYTIC APPLICATION; GOLD NANOPARTICLES; SUPEROXIDE ION; REDOX; OXIDATION; POLYANILINES;

D O I：

10.1007/s10904-015-0172-y

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The present study summarizes the preparation of p-toluenesulfonic acid (p-TsOH) doped PANI/M (M = Pt, Pd, Ag, and Ni) nanohybrid electrodes and the activity for hydrogen peroxide generation using the electrodes. The activity depended on the kinds of the metals. The improvement of durability was suggested in the case of PANI/Ag and PANI/Ni nanohybrids as compared to that of PANI. The UV-Vis absorption spectra for the electrode films gave the information of the redox behavior of PANI before and after the reactions. The obtained results are considered to be valuable for the sterilization use.

引用

页码：855 / 859

页数：5

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