Ammonia decomposition over iron in the presence of water vapor

被引：0

作者：

Arabczyk, W ^{[1
]}

Zamlynny, J ^{[1
]}

Moszynski, D ^{[1
]}

Kalucki, K ^{[1
]}

机构：

[1] Tech Univ Szczecin, Inst Chem & Environm Engn, PL-70322 Szczecin, Poland

来源：

POLISH JOURNAL OF CHEMISTRY | 2005年 / 79卷 / 09期

关键词：

ammonia decomposition; iron; water vapor;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ammonia decomposition over iron in the presence of water vapor has been studied. Water vapor retards this process, though no change of the apparent activation energy is observed. Despite noticeable influence of the water vapor on the rate of ammonia decomposition the sticking coefficient of ammonia on iron is not affected. Those observations were explained by the retardation of nitrogen molecules recombination on the iron surface due to the presence of oxygen atoms. The positive influence of water vapor on the rate of iron nitriding is also elucidated.

引用

页码：1495 / 1501

页数：7

共 15 条

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