Synthesis and chiroptical properties of ferrocene-[4]-helicenequinones: kinetic resolution of a planar-chiral diene

被引：31

作者：

Latorre, Alfonso ^{[1
]}

Urbano, Antonio ^{[1
]}

Carmen Carreno, M. ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Organ Modulo 01, E-28049 Madrid, Spain

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 28期

关键词：

ASYMMETRIC-SYNTHESIS; DERIVATIVES; FERROCENES; HELICENES;

D O I：

10.1039/c1cc12921j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Both enantiomers of ferrocene [4]-helicenequinone 6, showing planar and helical chiralities, have been synthesized with very high optical purities using, as the key step, a kinetic resolution process between planar-chiral racemic ferrocene diene 2 and enantiopure sulfinyl benzoquinone (S)-3.

引用

页码：8103 / 8105

页数：3

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