Rigid chiral carbocyclic clefts as building blocks for the construction of new supramolecular hosts

被引：25

作者：

Try, AC ^{[1
]}

Painter, L ^{[1
]}

Harding, MM ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 52期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/S0040-4039(98)02179-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and resolution of two chiral carbocyclic cleft molecules containing carbonyl groups on the periphery of the cavity are reported. These compounds are reminiscent of Troger's base but contain a smaller cleft and additional carbonyl (or alcohol) groups. X-ray crystal structures of the dibromo and dimethyl derivatives show that the dihedral angle between the two aromatic rings is 79 degrees and 85 degrees respectively. The dibromo derivative provides entry into new supramolecular hosts, via introduction of additional recognition groups into the cleft molecules. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：9809 / 9812

页数：4

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