Synthesis and luminescence properties of novel deep red emitting phosphors Li2MgGeO4:Mn4+

被引:21
作者
Cao, Renping [1 ]
Ceng, Dong [1 ]
Yu, Xiaoguang [1 ]
Guo, Siling [1 ]
Wen, Yufeng [1 ]
Zheng, Guotai [1 ]
机构
[1] Jinggangshan Univ, Coll Math & Phys, Jian 343009, Jiangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
Mn4+ ion; red phosphor; luminescence; solid state reaction; NITRIDE PHOSPHORS; CRYSTAL-FIELD; MN4+; EMISSION;
D O I
10.1142/S1793604715500460
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Novel deep red phosphor Li2MgGeO4:Mn4+ is synthesized by high temperature solid state reaction method in air. The strongest PL band peaking at similar to 671 nm in the range of 600-750 nm is due to the E-2 -> (4)A(2) transition of Mn4+ ion and the PLE spectra shows broad band peaking at similar to 323 within the range 220-550 nm owing to the (4)A(2) -> T-4(1) transitions of Mn4+ ion. The optimum Mn4+ doping concentration is about 0.4 mol.%. The luminous mechanism is explained by Tanabe-Sugano diagram of Mn4+ ion. The results indicate that red phosphor Li2MgGeO4:Mn4+ is a beneficial phosphor for use in white light-emitting-diodes (LEDs).
引用
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页数:4
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