Gas-phase residence time distribution in a falling-film microreactor

Industrial-scale performance of gas-liquid reactors can be difficult to optimise for very rapid or highly exothermic reactions. Microstructured reactors for laboratory measurements offer new opportunities for the study of these reactions by enabling precise heat management and fine control of reactor operating conditions. For accurate experimental study, characterisation of the flow conditions within these new reactor devices is essential. The present study examines experimental residence time distributions for the gas phase through a microstructured failing-film reactor, in order to develop an appropriate flow model for further study of gas-phase mass-transfer characteristics in the system. For the gas-phase residence time distribution experiments, the detection system involves a flow of oxygen containing ozone as a tracer gas with continuous monitoring of the concentration by UV-light absorption. The experimental results are used to model the flow behaviour in the gas volume over the gas-liquid contact zone as a series of continuous stirred tank reactors whose number is a simple function of the gas Reynolds number. The experimental results are compared with computational fluid dynamics calculations of the gas flow within the reactor. The comparison indicates a clear correlation of the flow model behaviour with the appearance of recirculation loops in the reaction chamber and the effect of the gas jet at the entrance of the gas-liquid contact zone. (c) 2005 Elsevier Ltd. All rights reserved.