One-Pot Synthesis of Core-Expanded Naphthalene Diimides: Enabling N-Substituent Modulation for Diverse n-Type Organic Materials

被引：61
|
作者：
Hu, Yunbin [1 ]
Qin, Yunke [1 ]
Gao, Xike [1 ]
Zhang, Fengjiao [2 ]
Di, Chong-an [2 ]
Zhao, Zheng [1 ]
Li, Hongxiang [1 ]
Zhu, Daoben [1 ,2 ]
机构：
[1] Chinese Acad Sci CAS, Shanghai Inst Organ Chem, Mat Sci Lab, Shanghai 200032, Peoples R China
[2] CAS, Key Lab Organ Solids, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
来源：
ORGANIC LETTERS | 2012年 / 14卷 / 01期
关键词：
THIN-FILM TRANSISTORS; HIGH-ELECTRON-MOBILITY; HIGH-PERFORMANCE; OPTICAL-PROPERTIES; PERYLENE DIIMIDES; MATERIALS DESIGN; SEMICONDUCTORS; DERIVATIVES; CIRCUITS; DYES;
D O I：
10.1021/ol203059r
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A mild and versatile one-pot synthesis of core-expanded naphthalene dilmides has been developed, which undergoes a nucleophilic aromatic substitution reaction and then an imidization reaction, allowing an easy and low-cost access to diverse n-type organic materials. Some newly synthesized compounds by this one-pot operation exhibited high electron mobility of up to 0.70 cm(2) V-1 s(-1) in ambient conditions.
引用
收藏
页码：292 / 295
页数：4
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