Nickel-on-charcoal-catalyzed reductions of aryl chlorides

被引：0

作者：

Lipshutz, BH ^{[1
]}

Tomioka, T ^{[1
]}

Sato, K ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

SYNLETT | 2001年

关键词：

aryl chlorides; dechlorination; heterogeneous catalysis; nickel-on-charcoal;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Exposure of (functionalized) aryl chlorides to catalytic quantities of nickel-on-charcoal in the presence of stoichiometric amounts of Me2NH . BH3/K2CO3 in refluxing acetonitrile leads to high yields of reduced arenes. PCBs are also reduced under these conditions. The method is highly tolerant of moisture.

引用

页码：970 / 973

页数：4

共 40 条

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