Nickel-on-charcoal-catalyzed reductions of aryl chlorides

被引：0
作者：
Lipshutz, BH [1 ]
Tomioka, T [1 ]
Sato, K [1 ]
机构：
[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
来源：
SYNLETT | 2001年
关键词：
aryl chlorides; dechlorination; heterogeneous catalysis; nickel-on-charcoal;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Exposure of (functionalized) aryl chlorides to catalytic quantities of nickel-on-charcoal in the presence of stoichiometric amounts of Me2NH . BH3/K2CO3 in refluxing acetonitrile leads to high yields of reduced arenes. PCBs are also reduced under these conditions. The method is highly tolerant of moisture.
引用
收藏
页码：970 / 973
页数：4
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