A new one-dimensional 4,4′-bipy-bridged compound [Mn(hfac)2(4,4′-bipy)]n (hfac = hexafluoroacetetylacetonato;: 4,4′-bipy = 4,4′-bipyridine).: Synthesis, crystal structure and magnetic properties

被引：27
|
作者：
Shen, HY
Liao, DZ [1 ]
Jiang, ZH
Yan, SP
Sun, BW
Wang, GL
Yao, XK
Wang, HG
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Cent Lab, Tianjin 300071, Peoples R China
来源：
POLYHEDRON | 1998年 / 17卷 / 11-12期
关键词：
one-dimensional compound; 4,4 '-bipy-bridged compound; crystal structure; magnetic properties;
D O I：
10.1016/S0277-5387(97)00481-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A one-dimensional 4,4'-bipy-bridged compound [Mn(hfac)(2)(4,4'-bipy)](n) (hfac = hexafluoroacetetylacetonato; 4,4'-bipy = 4,4'-bipyridine) has been prepared and its structure has been determined. The structure consists of a zigzag-one-dimensional chain in which Mn(II) ion is bridged by 4,4'-bipy. The coordination environment is distorted octahedral for Mn(II), and Mn(hfac)(2)(4,4'-bipy) has a cis coordination. Magnetic investigation shows that this compound presents a very weak antiferromagnetic interaction (J = -0.196 cm(-1), g(Mn) = 2.02, F = 2.24 x 10(-3)). (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1953 / 1957
页数：5
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