A high-voltage asymmetric electrical double-layer capacitors using propylene carbonate

被引:29
作者
Shen, Hsiao-Hsuan [1 ]
Hu, Chi-Chang [1 ]
机构
[1] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 30013, Taiwan
关键词
Carbon black; Potential window; Propylene carbonate; Activated carbon; Asymmetric supercapacitor; SUPERCAPACITORS; ELECTROLYTES; ELECTRODES; ENERGY;
D O I
10.1016/j.elecom.2016.06.015
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The upper limit of the double-layer potential window for the propylene carbonate/carbon black interface is effectively extended from 0.1 to 1 V (vs. Ag/AgNO3), compared with activated carbon. Commercial carbon black with low defects and activated carbon are respectively employed as positive and negative electrode materials to construct an advanced asymmetric supercapacitor with cell voltage reaching 3 V in propylene carbonate. This asymmetric supercapacitor of the double-layer type with a cell voltage of 3 V is very stable in 10,000-cycle charge-discharge tests. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:23 / 27
页数:5
相关论文
共 23 条
[1]   Carbons and Electrolytes for Advanced Supercapacitors [J].
Beguin, Francois ;
Presser, Volker ;
Balducci, Andrea ;
Frackowiak, Elzbieta .
ADVANCED MATERIALS, 2014, 26 (14) :2219-2251
[2]  
Bohli T., 2015, ENVIRON SCI POLLUT R, P1
[3]   To Be or Not To Be Pseudocapacitive? [J].
Brousse, Thierry ;
Belanger, Daniel ;
Long, Jeffrey W. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (05) :A5185-A5189
[4]   Nanostructured materials for the construction of asymmetrical supercapacitors [J].
Chae, J. H. ;
Ng, K. C. ;
Chen, G. Z. .
PROCEEDINGS OF THE INSTITUTION OF MECHANICAL ENGINEERS PART A-JOURNAL OF POWER AND ENERGY, 2010, 224 (A4) :479-503
[5]   1.9 V aqueous carbon-carbon supercapacitors with unequal electrode capacitances [J].
Chae, Jung Hoon ;
Chen, George Z. .
ELECTROCHIMICA ACTA, 2012, 86 :248-254
[6]   Cell voltage versus electrode potential range in aqueous supercapacitors [J].
Dai, Zengxin ;
Peng, Chuang ;
Chae, Jung Hoon ;
Ng, Kok Chiang ;
Chen, George Z. .
SCIENTIFIC REPORTS, 2015, 5
[7]   Asymmetric Supercapacitors Based on Graphene/MnO2 and Activated Carbon Nanofiber Electrodes with High Power and Energy Density [J].
Fan, Zhuangjun ;
Yan, Jun ;
Wei, Tong ;
Zhi, Linjie ;
Ning, Guoqing ;
Li, Tianyou ;
Wei, Fei .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (12) :2366-2375
[8]   Carbon materials for the electrochemical storage of energy in capacitors [J].
Frackowiak, E ;
Béguin, F .
CARBON, 2001, 39 (06) :937-950
[9]   Cathodic deposition of Ni(OH)2 and Co(OH)2 for asymmetric supercapacitors: Importance of the electrochemical reversibility of redox couples [J].
Hu, Chi-Chang ;
Chen, Jia-Cing ;
Chang, Kuo-Hsin .
JOURNAL OF POWER SOURCES, 2013, 221 :128-133
[10]   Degradation Responses of Activated-Carbon-Based EDLCs for Higher Voltage Operation and Their Factors [J].
Ishimoto, Shuichi ;
Asakawa, Yuichiro ;
Shinya, Masanori ;
Naoi, Katsuhiko .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (07) :A563-A571