Surface Modification of Zinc Oxide Nanorods with Zn-Porphyrin via Metal-Ligand Coordination for Photovoltaic Applications

被引：15

作者：

Koo, Jaehong ^{[2
]}

Cho, Jin-Ju ^{[2
]}

Yang, Jin Ho ^{[2
]}

Yoo, Pil J. ^{[3
]}

Oh, Kyung Wha ^{[1
]}

Park, Juhyun ^{[2
]}

机构：

[1] Chung Ang Univ, Dept Home Econ Educ, Seoul 156756, South Korea

[2] Chung Ang Univ, Sch Chem Engn & Mat Sci, Seoul 156756, South Korea

[3] Sungkyunkwan Univ, Sch Chem Engn, Suwon 440746, South Korea

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2012年 / 33卷 / 02期

关键词：

Zinc oxide; Nanorods; Porphyrin; Surface modification; Solar cells; DYES; COMPLEXES;

D O I：

10.5012/bkcs.2012.33.2.636

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We modify ZnO nanorods with Zn-porphyrin to obtain the improved characteristics of energy transfer, which is further investigated for the applicability to photovoltaic devices. A nitrogen heterocyclic ligand containing a thiol group is covalently grafted onto the surface of finely structured ZnO nanorods with a length of 50-250 nm and a diameter of 15-20 nm. Zn-porphyrin is then attached to the ligand molecules by the mechanism of metal-ligand axial coordination. The resulting energy band diagram suggests that the porphyrin-modified ZnO nanorods might provide an efficient pathway for energy transfer upon being applied to photovoltaic devices.

引用

页码：636 / 640

页数：5

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