The first report on the atom transfer radical polymerization of an optically active acidic monomer based on L-phenylalanine

被引：5

作者：

Mallakpour, Shadpour ^{[1
,2
]}

Rafiee, Zahra ^{[3
]}

机构：

[1] Isfahan Univ Technol, Dept Chem, Organ Polymer Chem Res Lab, Esfahan 8415683111, Iran

[2] Isfahan Univ Technol, Nanotechnol & Adv Mat Inst, Esfahan 8415683111, Iran

[3] Univ Yasuj, Dept Chem, Yasuj 75914353, Iran

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2012年 / 124卷 / 06期

关键词：

atom transfer radical polymerization; N-acryloyl-L-phenylalanine; controlled polymerization; water-soluble initiators; optically active; AQUEOUS-MEDIA; POLYMERS; METHACRYLATE;

D O I：

10.1002/app.35474

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

For the first time, acidic monomer chiral N-acryloyl-L-phenylalanine was polymerized directly by atom transfer radical polymerization under mild conditions. Controlled polymerization was carried out in pure water, methanol/water mixture, or pure methanol using water-soluble initiators, such as 2-hydroxyethyl-2'-methyl-2'-bromopropionate and sodium-4-(bromomethyl)benzoate at room temperature. The corresponding optically active biocompatible amino acid-based homopolymers were obtained in good yields with narrow molecular weight distributions. (c) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011

引用

页码：4512 / 4516

页数：5

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