Palladium catalyzed stereoselective cross-couplings and acylations of chiral secondary diorganozincs

被引：42
|
作者：
Boudier, A [1 ]
Knochel, P [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
来源：
TETRAHEDRON LETTERS | 1999年 / 40卷 / 04期
关键词：
stereoselective cross-coupling; palladium catalysis; alkenylation; acylation;
D O I：
10.1016/S0040-4039(98)02581-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cyclic and open-chain trisubstituted olefins were hydroborated with (-)-IpcBH(2) and stereoselectively transmetalated to the corresponding chiral zinc reagents with excellent diastereoselectivity and good enantioselectivity. The palladium(0) catalyzed cross-coupling with alkenyl iodides or acyl chlorides proceeds with high retention of configuration in satisfactory overall yields. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：687 / 690
页数：4
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