Solid-phase synthesis and encoding strategies for olefin polymerization catalyst libraries

被引:1
|
作者
Boussie, TR [1 ]
Coutard, C [1 ]
Turner, H [1 ]
Murphy, V [1 ]
Powers, TS [1 ]
机构
[1] Symyx Technol, Santa Clara, CA 95051 USA
关键词
combinatorial chemistry; heterogeneous catalysis; polymers; solid-phase synthesis;
D O I
10.1002/(SICI)1521-3773(19981217)37:23<3272::AID-ANIE3272>3.0.CO;2-R
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Active polymerization catalysts, novel resin-bound diimine complexes of nickel(II) and palladium(II) are obtained by combinatorial synthesis and combined in a catalyst library. By tagging with fluorescent markers, the catalysts can be coded. Therefore, after cleavage of the tag from the polymer-coated resin, HPLC can be used to determine the pathway along which the products were formed.
引用
收藏
页码:3272 / 3275
页数:4
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