Solid-phase synthesis and encoding strategies for olefin polymerization catalyst libraries

被引：1

作者：

Boussie, TR ^{[1
]}

Coutard, C ^{[1
]}

Turner, H ^{[1
]}

Murphy, V ^{[1
]}

Powers, TS ^{[1
]}

机构：

[1] Symyx Technol, Santa Clara, CA 95051 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1998年 / 37卷 / 23期

关键词：

combinatorial chemistry; heterogeneous catalysis; polymers; solid-phase synthesis;

D O I：

10.1002/(SICI)1521-3773(19981217)37:23<3272::AID-ANIE3272>3.0.CO;2-R

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Active polymerization catalysts, novel resin-bound diimine complexes of nickel(II) and palladium(II) are obtained by combinatorial synthesis and combined in a catalyst library. By tagging with fluorescent markers, the catalysts can be coded. Therefore, after cleavage of the tag from the polymer-coated resin, HPLC can be used to determine the pathway along which the products were formed.

引用

页码：3272 / 3275

页数：4

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