An STM study of chemically deposited silver nanoclusters on mixed self-assembled monolayers

被引：0
作者：
Grummt, UW
Geissler, M
Drechsler, T
Fuchs, H
Staub, R
机构：
[1] Univ Jena, Inst Chem Phys, D-07743 Jena, Germany
[2] Univ Munster, Inst Phys, D-4400 Munster, Germany
[3] Tech Univ Dresden, Inst Angew Photophys, D-8027 Dresden, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1998年 / 37卷 / 23期
关键词：
monolayers; nanostructures; scanning tunneling microscopy; silver;
D O I：
10.1002/(SICI)1521-3773(19981217)37:23<3286::AID-ANIE3286>3.0.CO;2-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Small silver clusters Ag(n) (primarily probably Ag4 clusters which aggregate to Ag(n) (400 &lt; n &lt; 2000)) are generated in the immediate vicinity of a four-electron reducing agent (based on hydroquinone) which is incorporated in a monolayer of long-chain alkanethiols. The hydroquinone derivative is oxidized to quinone (see the picture). Molecularly resolved scanning tunneling microscopy (STM) images were obtained of self-assembled monolayers with and without silver clusters.
引用
收藏
页码：3286 / 3289
页数：4
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