Electrochemical Li-Ion Intercalation in Octacyanotungstate-Bridged Coordination Polymer with Evidence of Three Magnetic Regimes

被引:20
作者
Long, Jerome [1 ]
Asakura, Daisuke [2 ]
Okubo, Masashi [3 ]
Yamada, Atsuo [3 ]
Guari, Yannick [1 ]
Larionova, Joulia [1 ]
机构
[1] Univ Montpellier, UMR UM CNRS ENSM 5253, Inst Charles Gerhardt Montpellier, Ingn Mol & Nanoobjets, Pl E Bataillon, F-34095 Montpellier, France
[2] Natl Inst Adv Ind Sci & Technol, Umezono 1-1-1, Tsukuba, Ibaraki, Japan
[3] Univ Tokyo, Sch Engn, Dept Chem Syst Engn, Bunkyo Ku, Hongo 7-8-1, Tokyo, Japan
基金
日本科学技术振兴机构;
关键词
PRUSSIAN BLUE ANALOGS; METAL-ORGANIC FRAMEWORKS; PHOTOINDUCED MAGNETIZATION; MULTIFUNCTIONAL MATERIALS; CATHODE MATERIALS; RED LUMINESCENCE; PHASE-TRANSITION; OPTICAL-ACTIVITY; BATTERIES; HEXACYANOFERRATE;
D O I
10.1021/acs.inorgchem.6b01086
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Discovery of novel compounds capable of electrochemical ion intercalation is a primary step toward development of advanced electrochemical devices such as batteries. Although cyano-bridged coordination polymers including Prussian blue analogues have been intensively investigated as ion intercalation materials, the solid-state electrochemistry of the octacyanotungstate-bridged coordination polymer has not been investigated. Here, we demonstrate that an octacyanotungstate-bridged coordination polymer Tb(H2O)(5)[W(CN)(8)] operates as a Li+-ion intercalation electrode material. The detailed magnetic measurements reveal that the tunable amount of intercalated Li+ ion in the solid-state redox reaction between paramagnetic [W-V(CN)(8)](3-) and diamagnetic [W-IV(CN)(8)](4-) in the framework enables the electrochemical control of different magnetic regimes. While the initial ferromagnetic long-range ordering is irreversibly lost upon lithium insertion, electrochemical switching between paramagnetic and short-range ordering regimes can be achieved.
引用
收藏
页码:7637 / 7646
页数:10
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