Synthesis of novel diketopyrrolopyrrole-based dyes

被引:4
|
作者
Punzi, Angela [1 ]
Zappimbulso, Nicola [1 ]
Farinola, Gianluca M. [1 ]
机构
[1] Univ Bari Aldo Moro, Dipartimento Chim, Via Orabona 4, I-70126 Bari, Italy
来源
MONATSHEFTE FUR CHEMIE | 2019年 / 150卷 / 01期
关键词
Chromophores; Carboxylic acids; Heterocycles; DSC; Absorption spectra; Donor-acceptor effects; SENSITIZED SOLAR-CELLS; DPP-BASED SENSITIZERS; PYRROLO-PYRROLE DPP; HIGHLY EFFICIENT; DERIVATIVES; UNIT;
D O I
10.1007/s00706-018-2282-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three novel diketopyrrolopyrrole-based molecules for potential application in dye-sensitized solar cells are synthesized starting from a common and easily available key intermediate with a bis-thienyl diketopyrrolopyrrole structure. The synthetic sequence is based upon transition-metal catalyzed coupling reactions involving commercial boronic acid followed by condensation reactions with 2-cyanoacetic acid. Absorption and fluorescence spectra of the molecules are also reported. [GRAPHICS] .
引用
收藏
页码:59 / 66
页数:8
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