Iridium-Catalyzed Silylation

被引：0

作者：

Iglesias, Manuel ^{[1
]}

Oro, Luis A. ^{[1
]}

机构：

[1] Univ Zaragoza, Dept Inorgan Chem, ISQCH, CSIC, Zaragoza, Spain

来源：

IRIDIUM CATALYSTS FOR ORGANIC REACTIONS | 2021年 / 69卷

关键词：

Catalysis; C-H bond functionalization; Dehydrogenative silylation; Hydrosilylation; Iridium; C-H SILYLATION; N-HETEROCYCLIC CARBENE; BLUE ORGANIC ELECTROPHOSPHORESCENCE; C(SP(3))-H BONDS ADJACENT; ONE-POT SYNTHESIS; DEHYDROGENATIVE SILYLATION; TERMINAL ALKYNES; ENANTIOSELECTIVE HYDROSILYLATION; ASYMMETRIC HYDROSILYLATION; ALKENE HYDROSILATION;

D O I：

10.1007/3418_2020_55

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this chapter, homogeneous iridium-catalyzed silylation reactions are reviewed, focusing primarily on their synthetic utility. Additionally, relevant catalytic cycles are commented, paying especial attention to those that are more representative of each type of process. The chapter is divided into two main types of reactions, namely, hydrosilylation and C-H bond silylation. The former deals with the hydrosilylation of polar unsaturated bonds (ketones and imines) and non-polar unsaturated bonds (alkenes and alkynes). The latter covers the directed and non-directed C-H bond silylation of alkenes, alkynes, arenes, and alkanes - mainly comprising dehydrogenative silylation reactions, which may occur in the presence or absence of a hydrogen acceptor.

引用

页码：227 / 270

页数：44

共 191 条

[1] Immobilization of chiral phosphine ligands on silica gel by means of the allylsilane method and their use for catalytic asymmetric reactions [J].

Aoki, K ;

Shimada, T ;

Hayashi, T .

TETRAHEDRON-ASYMMETRY, 2004, 15 (11) :1771-1777

[2] IRIDIUM COMPLEXES AS HYDROSILYLATION CATALYSTS [J].

APPLE, DC ;

BRADY, KA ;

CHANCE, JM ;

HEARD, NE ;

NILE, TA .

JOURNAL OF MOLECULAR CATALYSIS, 1985, 29 (01) :55-64

[3] From Remote Alkenes to Linear Silanes or Allylsilanes depending on the Metal Center [J].

Azpeitia, Susan ;

Rodriguez-Dieguez, Antonio ;

Garralda, Maria A. ;

Huertos, Miguel A. .

CHEMCATCHEM, 2018, 10 (10) :2210-2213

[4] A theoretical investigation of ruthenium-catalyzed alkene hydrosilation: Evidence to support an exciting new mechanistic proposal [J].

Beddie, C ;

Hall, MB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (42) :13564-13565

[5] Asymmetric hydrogenation of unfunctionalized, purely alkyl-substituted olefins [J].

Bell, S ;

Wüstenberg, B ;

Kaiser, S ;

Menges, F ;

Netscher, T ;

Pfaltz, A .

SCIENCE, 2006, 311 (5761) :642-644

[6] New Host Material for High-Performance Blue Phosphorescent Organic Electroluminescent Devices [J].

Bin, Jong-Kwan ;

Cho, Nam-Sung ;

Hong, Jong-In .

ADVANCED MATERIALS, 2012, 24 (21) :2911-2915

[7] B(C6F5)3-catalyzed hydrosilation of imines via silyliminium intermediates [J].

Blackwell, JM ;

Sonmor, ER ;

Scoccitti, T ;

Piers, WE .

ORGANIC LETTERS, 2000, 2 (24) :3921-3923

[8]

Blaser HU, 1999, CHIMIA, V53, P275

[9]

Blaser HU, 2002, ADV SYNTH CATAL, V344, P17, DOI 10.1002/1615-4169(200201)344:1<17::AID-ADSC17>3.0.CO

[10]

2-8

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