Lower rim substituted p-tert-butyl calix[4]arene; Part 14. Synthesis, structures and binding studies of calix[4]arene thioamides

被引：10

作者：

Bochenska, Maria ^{[1
]}

Kulesza, Joanna ^{[1
,3
]}

Chojnacki, Jaroslaw ^{[2
]}

Arnaud-Neu, Francoise ^{[3
]}

Hubscher-Bruder, Veronique ^{[3
]}

机构：

[1] Gdansk Univ Technol, Dept Chem Technol, Fac Chem, PL-80233 Gdansk, Poland

[2] Gdansk Univ Technol, Dept Inorgan Chem, PL-80233 Gdansk, Poland

[3] ECPM, CNRS, UDS, IPHC DSA,Lab Chim Phys, F-67087 Strasbourg 2, France

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2010年 / 68卷 / 1-2期

关键词：

p-tert-butylcalix[4]arene thioamides; Synthesis; Crystal structure; Liquid-liquid extraction; CATION COMPLEXATION; CRYSTAL-STRUCTURE; DERIVATIVES; ALKALI; AMIDES;

D O I：

10.1007/s10847-010-9735-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A number of p-tert-butylcalix[4]arene thioamides were synthesized and characterized by H-1-NMR and elemental analysis. Compounds 1-5 are O-substituted derivatives with -CH2-C(=S)-N-X groups, where NX = morpholidyl, NEt2, NHC2H4Ph, NHCH2Ph and NHEt, respectively. The X-ray structures of the ligands 1, 3, 5 and of the complex 3 center dot Pb(ClO4)(2), (compound 6), are presented and their slightly distorted cone conformation is established. The influence of the nature of the thioamide functions (secondary or tertiary) on the extractability of some selected metal cations was investigated. Whereas all these calixarenes show the highest extraction level for Ag+, tertiary thioamides are more efficient extractants for Pb2+ than secondary thioamides.

引用

页码：75 / 83

页数：9

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