Development of Hydrogen Recycling Systems for Petroleum Refineries: Hydrogen Sulfide Decomposition Using Titania Photocatalyst

被引：2

作者：

Takase, Mai ^{[1
]}

Furukawa, Shingo ^{[2
]}

Matsuda, Shun ^{[3
]}

Nishimori, Kei-ichi ^{[2
]}

Kanda, Yasuharu ^{[1
]}

机构：

[1] Muroran Inst Technol, Grad Sch Engn, Coll Environm Technol, Appl Chem Res Unit, 27-1 Mizumoto, Muroran, Hokkaido 0508585, Japan

[2] Muroran Inst Technol, Dept Appl Sci, 27-1 Mizumoto, Muroran, Hokkaido 0508585, Japan

[3] Muroran Inst Technol, Grad Sch Engn, Div Sustainable & Environm Engn, 27-1 Mizumoto, Muroran, Hokkaido 0508585, Japan

来源：

JOURNAL OF THE JAPAN PETROLEUM INSTITUTE | 2018年 / 61卷 / 06期

关键词：

Hydrogen sulfide; Decomposition; Hydrogen production; Titania;

D O I：

10.1627/jpi.61.361

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

H2S decomposition was examined in the gas and liquid phases over TiO2 photocatalyst. In the gas phase reaction, H-2 was obtained 16 using TiO2 as a photocatalyst. After the photocatalytic reaction, the color of TiO2 changed from white to yellow. SEM-EDS results revealed that sulfur was present on the TiO2 surface. H-2 evolution rate was remarkably higher in the liquid phase reaction than in the gas phase reaction. Thus, liquid phase reaction is optimal to obtain H-2 from the decomposition of H2S. Ethanolamine as a solvent of H2S underwent little photocatalytic decomposition. TiO2 photocatalyst has high potential for use in a new H-2 recycling process in the petroleum industry.

引用

页码：361 / 364

页数：4

共 6 条

[1] Correlation between Surface Area and Photocatalytic Activity for Acetaldehyde Decomposition over Bismuth Tungstate Particles with a Hierarchical Structure [J].