Preparation of Rh5@Ptx/C Core-Shell Nanoparticles for Electrocatalytic Oxidation of Ethanol

被引：0

作者：

Fang, Li ^{[1
]}

He, Jinlu ^{[1
]}

Saipanya, Surin ^{[2
]}

Huang, Xiaoping ^{[1
]}

机构：

[1] Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Shanxi, Peoples R China

[2] Chiang Mai Univ, Fac Sci, Dept Chem, Chiang Mai 50200, Thailand

来源：

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2015年 / 10卷 / 07期

关键词：

Rh@Pt/C; Core-shell Structure; Direct Ethanol Fuel Cell; Electrocatalytic oxidation; Cyclic voltammetry; PT-RH; METHANOL ELECTROOXIDATION; PERFORMANCE; CATALYSTS; ALLOY; PLATINUM; GROWTH; RU;

D O I：

暂无

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Rh-5@Pt-x/C core-shell nanoparticles were prepared by a two-step hydrogen reduction process and characterized by cyclic voltammetry (CV) combined with X-ray diffraction (XRD) and transmission electron microscopy (TEM). The effects of the thickness of Pt shell on the catalytic performance for ethanol oxidation were investigated for activity performance evaluation. It was also found that Rh core was practically covered by Pt shell with a strong interaction between Rh and Pt although there was no PtRh alloy formation at the surface of the Pt shell during the deposition process for the catalyst preparation. The Rh core remarkably enhanced the catalytic activity of Pt shell and promoted the breaking of C-C bonds of ethanol resulting in relatively lower potential for the ethanol reaction. It can also be concluded that the current density of the oxidation peak on Rh-5@Pt-5/C was ca. 64 % higher than that on Pt-5/C although they both showed rather similar characteristic peaks.

引用

页码：5350 / 5357

页数：8

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