catena-Poly[[bis(3-methylbenzoato-κ2O,O′)lead(II)]-μ-4,4′-bipyridine-κ2N:N′]

被引:4
作者
Xie, Jian-Ying [1 ]
Huang, Fu [1 ]
机构
[1] Guangdong Ocean Univ, Coll Sci, Zhanjiang 524088, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
data-to-parameter ratio = 15.9; indicators: single-crystal X-ray study; mean σ(C-C) = 0.004 Å; R factor = 0.017; T = 296 K; wR factor = 0.042;
D O I
10.1107/S1600536811035021
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Pb(C8H7O2)(2)(C10H8N2)](n), the Pb-II atom is located on a twofold rotation axis and is six-coordinated by four carboxylate O atoms from two 3-methylbenzoate ligands and two N atoms from two 4,4'-bipyridine (4,4'-bpy) ligands, displaying a hemi-directed coordination. The 4,4'-bpy ligand has an inversion center at the mid-point of the central C-C bond. The Pb-II atoms are linked by bidentate bridging 4,4'-bpy into a chain along [101]. These chains are further connected into layers via C-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码:M1326 / U234
页数:10
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