Effect of alloyed Lu, Hf and Cr on the oxidation and spallation behavior of NiAl

被引:67
作者
Zhao, Chunshan [1 ]
Zhou, Yuhua [1 ]
Zou, Zhonghua [1 ]
Luo, Lirong [1 ]
Zhao, Xiaofeng [1 ]
Guo, Fangwei [1 ]
Xiao, Ping [2 ]
机构
[1] Shanghai Jiao Tong Univ, Shanghai Key Lab Adv High Temp Mat & Precis Formi, Shanghai 200240, Peoples R China
[2] Univ Manchester, Sch Mat, Grosvenor St, Manchester M1, Lancs, England
基金
英国工程与自然科学研究理事会; 中国国家自然科学基金;
关键词
Intermetallics; Rare earth elements; Photoluminescence piezospectroscopy; Oxidation; Segregation; HIGH-TEMPERATURE OXIDATION; ALUMINA SCALE GROWTH; CYCLIC OXIDATION; MECHANICAL-PROPERTIES; REACTIVE ELEMENTS; IMAGE-ANALYSIS; OXIDE SCALES; AL ALLOYS; MINOR DY; COATINGS;
D O I
10.1016/j.corsci.2017.07.016
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The influences of alloyed Lu, Hf and Cr on the oxidation and spallation behavior of NiAl were investigated. Although Lu has a "block effect" of Al as Hf does, the oxidation rate of Lu-doped NiAl is significantly higher, due to: (1) inhibitation of theta- to alpha-Al2O3 transformation in early oxidation stage; (2) stronger scale grain refinement effect and enhanced oxygen transport rate. Segregation of S and C occurs not only at the alloy/scale interface, but also within the scale. Both Lu and Hf can significantly improve the scale adherence. However, This beneficial effect can be easily overcompensated by Cr.
引用
收藏
页码:334 / 343
页数:10
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