The first examples of Mo2Ru2S2 cluster compounds obtained through a new type of reaction. Crystal structure of [(eta(5)-MeO(2)CC(5)H(4))(2)(mu(3)-CO)(2)Mo2Ru2(mu(3)-S)(2)(CO)(6)]

被引:9
作者
Song, LC [1 ]
Wang, JQ [1 ]
Hu, QM [1 ]
Huang, XY [1 ]
机构
[1] STATE KEY LAB STRUCT CHEM,FUZHOU 350002,FUJIAN,PEOPLES R CHINA
基金
中国国家自然科学基金;
关键词
D O I
10.1016/0277-5387(96)00208-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of [eta(5)-RC(5)H(4)(CO)(mu-SPh)Mo](2) with Ru-3(CO)(12) in refluxing xylene afforded two novel cluster compounds, [(eta(5)-RC(5)H(4))(2)(mu(3)-CO)(2)Mo2Pu2(mu(3)-S)(2)(CO)(6)] (R = H, MeO(2)C), the structure for the cluster with R = MeO(2)C being unequivocally confirmed by X-ray diffraction techniques. Copyright (C) 1996 Elsevier Science Ltd
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页码:4295 / 4298
页数:4
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