CO2 Adsorption Over Metal-Organic Frameworks: A Mini Review

被引：43
|
作者：
Chen, Chao [1 ,2 ]
Lee, Yu-Ri [1 ]
Ahn, Wha-Seung [1 ]
机构：
[1] Inha Univ, Dept Chem & Chem Engn, Inchon 402751, South Korea
[2] Xinyang Normal Univ, Coll Chem & Chem Engn, Xinyang 464000, Henan Province, Peoples R China
来源：
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2016年 / 16卷 / 05期
关键词：
CO2; Adsorption; Metal-Organic Frameworks (MOFs); Open Metal Sites; Surface Functionalization; Interpenetration; Ion-Exchange; CARBON-DIOXIDE CAPTURE; GAS-ADSORPTION; CALCIUM-OXIDE; FLUE-GAS; MIL-101(CR) NANOPARTICLES; H-2; ADSORPTION; HIGH-CAPACITY; ACID SITES; HYDROGEN; SEPARATION;
D O I：
10.1166/jnn.2016.10971
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-organic frameworks (MOFs) are a class of porous materials that are comprised of metal ion-containing nodes linked by multi-dentate organic ligand bridges principally through coordination bonding. Over the last few decades, MOFs have been studied widely as CO2 adsorbents. CO2 adsorption in MOFs can be enhanced by tuning their physicochemical properties. This short review discusses CO2 adsorption over MOFs with particular focus on the contributory effects of (1) inherent textural properties, (2) coordinatively unsaturated open metal sites, (3) surface functionalization, (4) structural interpenetration (catenation), and (5) ion-exchange.
引用
收藏
页码：4291 / 4301
页数：11
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