Crystal to Calcite: Fabrication of Pure Calcium Carbonate Polymorph in the Solid State

被引:15
作者
Borah, Ballav Moni [1 ]
Dey, Sandeep Kumar [1 ]
Das, Gopal [1 ]
机构
[1] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, Assam, India
关键词
MAGNESIAN CALCITES; ORGANIC FRAMEWORK; ARAGONITE; VATERITE; GROWTH; CRYSTALLIZATION; PHASE; CACO3; PRECIPITATION; NUCLEATION;
D O I
10.1021/cg101534n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Selective formation of different polymorphs of calcium carbonate (CaCO3) in the solid state using aromatic organic acids as ligands for Ca2+ coordination has been reported. The formation of pure calcite and vaterite phase in bulk amount can be nicely captured by the choice of suitable solid state routes, employed in the preparation of precursor Ca-carboxylic acid complexes. Calcite can be solely obtained via crystallization of Ca-carboxylic acid complexes in a water methanol binary solvent system followed by thermal agitation at 600 C for 6 h. However, vaterite has been primarily obtained under similar conditions upon heating the crystalline powders of the precursory complexes prepared by the solid state grinding technique. The results obtained suggest that solid state techniques could give an alternative and versatile tool for controlling both the structure and the polymorphism of inorganic materials. The formation of intertwined aragonite rods from using trimesic acid as an organic additive instead of ligand is also noteworthy.
引用
收藏
页码:2773 / 2779
页数:7
相关论文
共 58 条
[1]   A CHEMICAL-MODEL FOR THE COOPERATION OF SULFATES AND CARBOXYLATES IN CALCITE CRYSTAL NUCLEATION - RELEVANCE TO BIOMINERALIZATION [J].
ADDADI, L ;
MORADIAN, J ;
SHAY, E ;
MAROUDAS, NG ;
WEINER, S .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1987, 84 (09) :2732-2736
[2]   Oriented growth of calcite controlled by self-assembled monolayers of functionalized alkanethiols supported on gold and silver [J].
Aizenberg, J ;
Black, AJ ;
Whitesides, GH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) :4500-4509
[3]   Factors involved in the formation of amorphous and crystalline calcium carbonate: A study of an ascidian skeleton [J].
Aizenberg, J ;
Lambert, G ;
Weiner, S ;
Addadi, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (01) :32-39
[4]  
[Anonymous], 1928, The Collected Works, Volume 1, Thermodynamics
[5]  
[Anonymous], 1995, SMART SAINT XPREP
[6]  
[Anonymous], 1999, SADABS:Software for Empirical Absorption Correction
[7]  
[Anonymous], 2001, Biomineralization: principles and concepts in bioinorganic materials chemistry
[8]   Modified calcite deposition due to ultrathin organic films on silicon substrates [J].
Archibald, DD ;
Qadri, SB ;
Gaber, BP .
LANGMUIR, 1996, 12 (02) :538-546
[9]   Control of crystal phase switching and orientation by soluble mollusc-shell proteins [J].
Belcher, AM ;
Wu, XH ;
Christensen, RJ ;
Hansma, PK ;
Stucky, GD ;
Morse, DE .
NATURE, 1996, 381 (6577) :56-58
[10]   TOTAL ALIGNMENT OF CALCITE AT ACIDIC POLYDIACETYLENE FILMS - COOPERATIVITY AT THE ORGANIC-INORGANIC INTERFACE [J].
BERMAN, A ;
AHN, DJ ;
LIO, A ;
SALMERON, M ;
REICHERT, A ;
CHARYCH, D .
SCIENCE, 1995, 269 (5223) :515-518