Calix [4]-bis-monothiacrown-5 as a versatile building block for homo- and heterometallic coordination polymers

被引：7
|
作者：
Park, In-Hyeok
Kim, Ja-Yeon
Lee, Eunji
Ju, Huiyeong
Kim, Seulgi
Lee, Joon-Hwa
Lee, Shim Sung [1 ]
机构：
[1] Gyeongsang Natl Univ, Dept Chem, Jinju 52828, South Korea
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2016年 / 70卷
关键词：
Calixarene; Mercury; Potassium; Exocoordination; Coordination polymer; MIXED-DONOR MACROCYCLES; CRYSTAL-STRUCTURES; METAL-COMPLEXES; ANION; NETWORKING; CHEMISTRY; MERCURY(II); HARD; FRAMEWORKS; SILVER(I);
D O I：
10.1016/j.inoche.2016.06.015
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Exocoordination-based homonuclear and heteronuclear coordination polymers of calix [4]-bis-monothiacrown-5 (L) are reported. L reacts with HgCl2 and affords a one-dimensional (1D) coordination polymer [L(mu-Hg2Cl4)](n) (1) linked by neutral square-type Hg2Cl4 clusters. A straightforward one-pot reaction of L with a mixture of HgCl2 and KCl resulted in the isolation of a heteronuclear species [(K2L)(mu-Hg3Cl8)](n) (2) adopting a 1D polymeric structure in which the endocyclic dipotassium(I) complex cation units of L are linked by anionic open double-square type (mu-Hg3Cl8)(2-) clusters. Both products form a pseudo 3D framework via interchain H-bonds and their topological analyses were also carried out. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：205 / 209
页数：5
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