Synthesis of polymer-supported rhodium(I)-1,3-bis(diphenylphosphino)propane moieties and their use in the heterogeneous hydrogenation of quinoline and benzylideneacetone

被引：25
作者：
Bianchini, C [1 ]
Frediani, M [1 ]
Mantovani, G [1 ]
Vizza, F [1 ]
机构：
[1] CNR, Ist Studio Stereochim & Energet Composti Coor, I-50132 Florence, Italy
来源：
ORGANOMETALLICS | 2001年 / 20卷 / 13期
关键词：
D O I：
10.1021/om0010868
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A p-styrenyl substituent attached to the ligand framework allows the diphosphine moiety -(C6H4)CH2-OCH2C(CH3)(CH2PPh2)(2) to be introduced as a pendant group in cross-linked styrene/divinylbenzene matrixes via free-radical copolymerization. In conjunction with rhodium(I), the POLYDIPHOS material forms an effective heterogeneous catalyst for the hydrogenation of benzylideneacetone to benzylacetone and of quinoline to a mixture-of 1,2,3,4-tetrahydraquinoline, 5,6,7,8-tetrahydroquinoline, and decahydroquinoline. The homogeneous behavior of related 1,3-bis(diphenylphosphino)-propane rhodium complexes is different in both activity and selectivity.
引用
收藏
页码：2660 / 2662
页数：3
相关论文
共 22 条
  • [1] [Anonymous], ENCY INORGANIC CHEM
  • [2] AUGUSTINE RL, 1996, HETEROGENEOUS CATALY, P356
  • [3] Novel heterogenized palladium(II) complexes anchored to polymer matrices functionalized with bis(diphenylphosphino)methane moieties
    Benvenuti, F
    Carlini, C
    Marchionna, M
    Patrini, R
    Galletti, AMR
    Sbrana, G
    [J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS, 1997, 7 (03): : 183 - 201
  • [4] Hydrogenation of organic substrates by an heterogenized catalyst based on a bis(diphenylphosphino)methane polymer-bound palladium(II) complex
    Benvenuti, F
    Carlini, C
    Marchionna, M
    Galletti, AMR
    Sbrana, G
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 145 (1-2) : 221 - 228
  • [5] 1,3-butadiene telomerization with methanol catalyzed by heterogenized palladium complexes
    Benvenuti, F
    Carlini, C
    Galletti, AMR
    Sbrana, G
    Marchionna, M
    Patrini, R
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 137 (1-3) : 49 - 63
  • [6] Bianchini C, 2001, EUR J INORG CHEM, P43
  • [7] Preparation, characterization, and performance of tripodal polyphosphine rhodium catalysts immobilized on silica via hydrogen bonding
    Bianchini, C
    Burnaby, DG
    Evans, J
    Frediani, P
    Meli, A
    Oberhauser, W
    Psaro, R
    Sordelli, L
    Vizza, F
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (25) : 5961 - 5971
  • [8] Bianchini C, 2001, ADV SYNTH CATAL, V343, P41, DOI 10.1002/1615-4169(20010129)343:1<41::AID-ADSC41>3.3.CO
  • [9] 2-G
  • [10] Preparation, characterization, and performance of the supported hydrogen-bonded ruthenium catalyst [(sulphos)Ru(NCMe)3](OSO2CF3)/SiO2.: Comparisons with analogous homogeneous and aqueous-biphase catalytic systems in the hydrogenation of benzylideneacetone and benzonitrile
    Bianchini, C
    Dal Santo, V
    Meli, A
    Oberhauser, W
    Psaro, R
    Vizza, F
    [J]. ORGANOMETALLICS, 2000, 19 (13) : 2433 - 2444
123