The crystal structure of the first ether solvate of hexaphenyldistannane [(Ph3Sn)2•2 THF]

被引:11
|
作者
Bauer, Jonathan O. [1 ]
机构
[1] Univ Regensburg, Fak Chem & Pharm, Inst Anorgan Chem, Univ Str 31, D-93053 Regensburg, Germany
关键词
crystalline solvates; inclusion compounds; stannanes; tin; weak interactions; X-ray crystallography; MOLECULAR-STRUCTURE; TRIVALENT CARBON; HYDROGEN; ANALOGS; POLYMORPHISM; ANIONS; BONDS; TIN;
D O I
10.1515/mgmc-2020-0001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Structural investigations of molecular crystal solvates can provide important information for the targeted crystallization of particular inclusion compounds. Here, the crystal structure of the first ether solvate of hexaphenyldistannane [(Ph3Sn)(2)center dot 2 THF] is reported. Structural features in terms of host-guest interactions and in the context of the previously reported polymorphs and solvates of (Ph3Sn)(2) are discussed.
引用
收藏
页码:1 / 6
页数:6
相关论文
共 50 条
  • [31] Studies of stannylated-1,2-dithiolato compounds:: Synthesis and crystal structure of co-crystalline 4,5-bis[(triphenylstannyl)methylthiolato]-1,2-dithiole-3-thione (Ph3SnCH2)2(dmt) and 5-[(triphenylstannyl)methylthiolato]-4-[(triphenylstannyl)thiolato]-1,2-dithiole-3-thione (Ph3SnCH2)(Ph3Sn)(dmt) [72:28]
    Bordinhao, Jairo
    Comerlato, Nadia M.
    Cortas, Laila de Castro
    Ferreira, Glaucio Braga
    Howie, R. Alan
    Wardell, James L.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (04) : 763 - 768
  • [32] New Solvate Polymorphs of Lanthanide Trisacetylacetonates: Crystal Structures of [Ln(acac)3(H2O)2] • Solv (Ln = Eu, Dy; Solv = Thf, H2O + EtOH, MeOH)
    Ilyukhin, A. B.
    Gavrikov, A. V.
    Dobrokhotova, Zh. V.
    Novotortsev, V. M.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2018, 63 (09) : 1186 - 1191
  • [33] Synthesis and Crystal Structure of [Li8(H2O)29][Sn10O4S20]•2H2O
    Kaib, Thomas
    Kapitein, Manuel
    Dehnen, Stefanie
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (12): : 1683 - 1686
  • [34] Crystal structure and low-temperature physical properties of CePd0.427Sn2
    Tursina, Anna
    Nesterenko, Sergey
    Gnida, Daniel
    Pikul, Adam Piotr
    Kaczorowski, Dariusz
    JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 667 : 282 - 286
  • [35] On the divergent reactivity of allenylstannanes generated from the O-directed free radical hydrostannation reaction of (±)-trans-3-(2-phenylcyclopropyl)prop-2-yn-1-ol. EPR evidence for the reversible addition of Ph3Sn radicals to vinyl triphenyltins
    Hale, K. Lawrence E.
    Fielding, Alistair J.
    Hale, Karl J.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2025, 23 (17) : 4116 - 4130
  • [36] Synthesis and crystal structures of the new four-membered tin-chalcogen rings [{Cp(Ph3P)Ni}(2)Cl2Sn2E2] (E=Se, S)
    Kraus, H
    Merzweiler, K
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (05): : 635 - 638
  • [37] Preparation and crystal structure of Na2Sn2Se5 -: A novel chalcogenostannate(IV) with layered complex anions
    Klepp, KO
    Hainz, M
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (04): : 863 - 866
  • [38] The [Sn5]2- cluster compound [K-(2,2,2-crypt)]2Sn5 -: Synthesis, crystal structure, Raman spectrum, and hierarchical relationship to CaIn2
    Somer, M
    Carrillo-Cabrera, W
    Peters, EM
    Peters, K
    Kaupp, M
    von Schnering, HG
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (01): : 37 - 42
  • [39] Synthesis, Structure, and Spectroscopy of the Biscarboranyl Stannylenes (bc)Sn•THF and K2[(bc)Sn]2 (bc=1,1′(ortho-Biscarborane)) and Dibiscarboranyl Ethene (bc)CHCH(bc)
    Phung, Alice C.
    Fettinger, James C.
    Power, Philip P.
    ORGANOMETALLICS, 2023, 42 (13) : 1649 - 1657
  • [40] Crystal Structure of 1-(2-Pyridiniomethyl)-2,4-bis(phenylsulfonyl)benzene Chloride Ethanol Solvate
    A. N. Chekhlov
    Russian Journal of General Chemistry, 2004, 74 : 944 - 948