The crystal structure of the first ether solvate of hexaphenyldistannane [(Ph3Sn)2•2 THF]

被引：11

作者：

Bauer, Jonathan O. ^{[1
]}

机构：

[1] Univ Regensburg, Fak Chem & Pharm, Inst Anorgan Chem, Univ Str 31, D-93053 Regensburg, Germany

来源：

MAIN GROUP METAL CHEMISTRY | 2020年 / 43卷 / 01期

关键词：

crystalline solvates; inclusion compounds; stannanes; tin; weak interactions; X-ray crystallography; MOLECULAR-STRUCTURE; TRIVALENT CARBON; HYDROGEN; ANALOGS; POLYMORPHISM; ANIONS; BONDS; TIN;

D O I：

10.1515/mgmc-2020-0001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Structural investigations of molecular crystal solvates can provide important information for the targeted crystallization of particular inclusion compounds. Here, the crystal structure of the first ether solvate of hexaphenyldistannane [(Ph3Sn)(2)center dot 2 THF] is reported. Structural features in terms of host-guest interactions and in the context of the previously reported polymorphs and solvates of (Ph3Sn)(2) are discussed.

引用

页码：1 / 6

页数：6

共 50 条

[11] Cationic bronsted acids for the preparation of SnIV salts:: Synthesis and characterisation of [Ph3Sn(OEt2)][H2N{B(C6F5)3}2], [Sn(NMe2)3(HNMe2)2][B(C6F5)4] and [Me3Sn(HNMe2)2][B(C6F5)4]
Sarazin, Yann
Coles, Simon J.
Hughes, David L.
Hursthouse, Michael B.
Bochmann, Manfred
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (16) : 3211 - 3220
[12] Crystal structure of [(Ph(Me)C:N:C(H)Ph)K•(tBuOK)2• (thf)2]∞:: A unimetallic mixed anion model for a "superbase"?
Andrews, PC
Fallon, GD
Maguire, M
Peatt, AC
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2000, 39 (24) : 4516 - +
[13] SYNTHESIS AND CRYSTAL-STRUCTURE OF [(CP(CO)(2)FE)(2)SN(F)FBF3]
MERZWEILER, K
WEISSE, L
KRAUS, H
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (03): : 425 - 429
[14] Synthesis and structural characterization of tin(IV) N-nitroso-N-phenylhydroxylaminato complexes:: Crystal structures of Sn(O2N2Ph)4, Ph2Sn(O2N2Ph)2 and [Me2Sn(O2N2Ph)2]2
Deák, A
Venter, M
Kálmán, A
Párkányi, L
Radics, L
Haiduc, I
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2000, (01) : 127 - 132
[15] Bridging cyclopentadienyl M-Sn(IV) bonded polymetallic complexes:: X-ray crystal structures of [(Me2SnCl)(CO)3MoC5H4C(O)CH2]2•CH2Cl2 and [(Ph3Sn)(CO)3WC5H4C(O)CH2]2•3H2O
Tang, LF
Chai, JF
Wang, ZH
Jia, WL
Wang, JT
POLYHEDRON, 2001, 20 (05) : 403 - 408
[16] Synthesis and crystal structure of the mixed valent complex [Sn2I3(NPPh3)3]
Chitsaz, S
Neumüller, B
Dehnicke, K
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (04): : 813 - 815
[17] Synthesis and reactions of 1-t-butyldimethylsilyl-2,3-diphenyl-1-aza-3-phosphaallyl lithium and potassium.: Crystal structures of [M{P(Ph)C(Ph)NSiMe2But}(L)]2 (M = Li, L = THF; M = K, L = Et2O), [Sn{P(Ph)C(Ph)NSiMe2But}2] and [P(Ph)C(Ph)=NSiMe2But]2
Wang, ZX
Wang, DQ
Dou, JM
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 665 (1-2) : 205 - 213
[18] The Crystal Structure of Ni21Sn2P6
Schmetterer, Clemens
Wildner, Manfred
Giester, Gerald
Richter, Klaus W.
Ipser, Herbert
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2009, 635 (02): : 301 - 306
[19] Synthesis, Crystal and Electronic Structure of [K[18]crown-6)]2[Sn2Bi2]
Lips, Felicitas
Raupach, Marc
Massa, Werner
Dehnen, Stefanie
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (7-8): : 859 - 863
[20] The Crystal Structure of a RAS (N-CH3-2-NH2-5-Cl-Py)(TCNQ)(CH3CN) Solvate
Starodub, T. N.
Fenske, D.
Fuhr, O.
Kazheva, O. N.
Starodub, V. A.
CRYSTALLOGRAPHY REPORTS, 2020, 65 (02) : 242 - 246

← 1 2 3 4 5 →