Conductive polymer composite materials and their utility in electromagnetic shielding applications

被引:31
作者
Fox, Richard T. [2 ]
Wani, Vijay [3 ]
Howard, Kevin E. [1 ]
Bogle, Andrew [4 ]
Kempel, Leo [4 ]
机构
[1] Dow Chem Co USA, New Prod R&D, Core R&D, Midland, MI 48674 USA
[2] Dow Chem Co USA, Plast Dow Bldg Solut, Midland, MI 48674 USA
[3] Dow Chem Co USA, Plast Mat Res, Freeport, TX USA
[4] Michigan State Univ, Dept Elect & Comp Engn, E Lansing, MI 48824 USA
关键词
composites; compounding; conducting polymers; fibers; fillers; injection molding;
D O I
10.1002/app.27317
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Commercial electronic devices require shielding solutions that ensure electromagnetic compatibility (EMC) while accounting for effects of specific enclosure structural features such as seams, vents, and port dimensions. In practice, suitable EMC materials combine with the device operating characteristics to determine an overall shielding response. To optimally couple plastic design practices with EMC requirements, both polymer materials science and electrical engineering concepts, must be considered. Use of extrinsically conductive polymer (ECP) formulations for electronic applications has advantages in that they can be directly molded to a desired shape and serve to provide the necessary shielding while also meeting mechanical integrity requirements. Shielding and mechanical performance can be varied via filler loading or altered through wall thickness changes to satisfy demands associated with a particular device. Injection-moldable ECP polycarbonate-based formulations can attain average shielding effectiveness (SE) levels of similar to 50-60 dB through 2 GHz at 2-mm thickness as measured using ASTM D 4935 procedures. These values vary with thickness, and SE improvements of similar to 10-20 dB are observed when increasing from I to 2 mm. Additionally, resultant mechanical properties of shielding composites are strong functions of overall fiber content. These interrelated material and shielding characteristics, which form the basis for filled conductive polymer use within practical enclosure shielding designs, are described. (c) 2007 Wiley Periodicals, Inc.
引用
收藏
页码:2558 / 2566
页数:9
相关论文
共 24 条
[1]  
[Anonymous], 1999, D493599 ASTM
[2]  
Archambeault B. R., 2002, PCB DESIGN REAL WORL
[3]  
BARNES JR, 1987, EL SYSTEM DESIGN INT
[4]   ELECTRICAL TRANSPORT-PROPERTIES NEAR A CLASSICAL CONDUCTIVITY OR PERCOLATION-THRESHOLD [J].
BERGMAN, DJ .
PHYSICA A, 1989, 157 (01) :72-88
[5]  
Bicerano J, 1999, J MACROMOL SCI R M C, VC39, P561
[6]   Investigation of the conductivity of random networks [J].
Bigalke, J .
PHYSICA A, 1999, 272 (3-4) :281-293
[7]   PLASTIC COMPOSITES FOR ELECTROMAGNETIC-INTERFERENCE SHIELDING APPLICATIONS [J].
BIGG, DM ;
STUTZ, DE .
POLYMER COMPOSITES, 1983, 4 (01) :40-46
[8]  
BIGG DM, 1986, METAL FILLED POLYM P, pCH3
[9]   Effects of molding conditions on the electromagnetic interference performance of conductive ABS parts [J].
Chen, SC ;
Chien, RD ;
Lee, PH ;
Huang, JS .
JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 98 (03) :1072-1080
[10]   Effect of mixing process on electromagnetic interference shielding effectiveness of nickel/acrylonitrile-butadiene-styrene composites [J].
Chou, KS ;
Huang, KC ;
Shih, ZH .
JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 97 (01) :128-135