The Removal of Cationic Dyes from Aqueous Solutions by Using Poly(N-Vinylpyrrolidone-co-Methacrylic Acid) Hydrogel Adsorbents: Effects of pH and Composition on Adsorption

被引:6
作者
Torun, Murat [1 ]
Solpan, Dilek [1 ]
机构
[1] Hacettepe Univ, Dept Chem, TR-06800 Beytepe, Turkey
关键词
Hydrogel; Poly(N-vinylpyrrolidone-co-methacrylicacid); Swelling; Adsorption; Cationic dyes; POLYMER;
D O I
10.1007/s12221-015-0735-0
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
In this study, poly(N-vinylpyrrolidone-co-methacrylic acid) (P(VP/MAA)) hydrogels prepared with gamma-radiation were used for swelling, diffusion, and uptake of some cationic dyes which are Janus Green B (JGB) and Magenta (M). P(VP/MAA) hydrogels irradiated at 3.4 kGy were employed for swelling and diffusion studies in water and cationic dye solutions. The influence of dose, pH, relative amounts of monomers in VP/MAA monomer mixtures on swelling properties were investigated. P(VP/MAA) hydrogels were swollen in distilled water at pH 4.0, 7.0, and 9.0. P(VP/MAA) hydrogel containing 5 mole% methacrylic acid showed the maximum % swelling at pH 9.0 in water. Adsorption isotherms were plotted for JGB and M in P(VP/MAA) hydrogel systems. Consequently, it may be concluded that crosslinked P(VP/MAA) hydrogels may be successfully used in the purification of waste water containing certain textile dyes.
引用
收藏
页码:735 / 743
页数:9
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