Synthesis of α-functionalized ketones by visible-light promoted oxygenation of alkenes

被引：11
作者：
Gong, Xinchi [1 ]
Zhu, Chunyin [1 ]
Ye, Long-Wu [2 ]
机构：
[1] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China
[2] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2020年 / 18卷 / 10期
基金：
中国国家自然科学基金;
关键词：
PHOTOREDOX CATALYSIS; PHENACYL IODIDES; RADICAL-ADDITION; DIFUNCTIONALIZATION; MIGRATION; STYRENES; GOLD;
D O I：
10.1039/c9ob02754h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This article gives a short review on the visible-light promoted synthesis of alpha-functionalized ketones from alkenes. Various alpha-functionalized ketones, including alpha-halo, sulfinyl/sulfonyl, aryl, azido and thiocyanato ketones can be synthesized from the reaction of alkenes with different radical species generated by visible-light catalysis. These transformations typically use dioxygen as the terminal oxidant and do not require a transition metal to activate the double bond, which is quite different from the transition-metal catalysed reactions (Wacker oxidation or hydroformylation).
引用
收藏
页码：1843 / 1850
页数：8
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