Solvothermal Synthesis, Characterization, and Formation Mechanism of a Single-Layer Anatase TiO2 Nanosheet with a Porous Structure

被引：24

作者：

Chen, Yajie ^{[1
]}

Tian, Guohui ^{[1
]}

Ren, Zhiyu ^{[1
]}

Tian, Chungui ^{[1
]}

Pan, Kai ^{[1
]}

Zhou, Wei ^{[1
]}

Fu, Honggang ^{[1
]}

机构：

[1] Heilongjiang Univ, Key Lab Funct Inorgan Mat Chem, Minist Educ Peoples Republ China, Harbin 150080, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 05期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

Titanium; Nanostructures; Solvothermal synthesis; Microporous materials; Raman spectroscopy; SURFACE-ENHANCED RAMAN; PHOTOCATALYTIC ACTIVITY; SILVER; GOLD; SCATTERING; ROUTE; FABRICATION; ADSORPTION; SPHERES; FILMS;

D O I：

10.1002/ejic.201000999

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel single-layer polycrystalline anatase TiO2 (SLP TiO2) nanosheet with porous structure was synthesized through a simple solvothermal method by employing rod-like titanyl sulfate as the starting material in the presence of glycerol, followed by calcination. SEM, TEM, X-ray diffraction, FTIR spectroscopy, thermogravimetry coupled to FTIR spectroscopy, solid-state C-13 NMR spectroscopy, and N-2 adsorption/desorption processes were employed to investigate the structure of the products. The structure and morphology were found to be dependent on the experimental conditions, such as solvothermal reaction time, morphology of titanyl sulfate, and solvent type. The obtained SLP TiO2 nanosheet was employed as a support for loading well-dispersed Ag nanoparticles and proved to be a good surface-enhanced Raman scattering (SERS) substrate for the detection of 4-aminothiophenol and Rhodamine 6G, showing great potential as a convenient and powerful substrate for SERS studies in the field of detecting different target molecules due to good uniformity and reliability.

引用

页码：754 / 760

页数：7

共 47 条

[1] TiO2-B nanowires [J].

Armstrong, AR ;

Armstrong, G ;

Canales, J ;

Bruce, PG .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (17) :2286-2288

[2] Graphoepitaxy of self-assembled block copolymers on two-dimensional periodic patterned templates [J].

Bita, Ion ;

Yang, Joel K. W. ;

Jung, Yeon Sik ;

Ross, Caroline A. ;

Thomas, Edwin L. ;

Berggren, Karl K. .

SCIENCE, 2008, 321 (5891) :939-943

[3] Colloidal semiconductor/magnetic heterostructures based on iron-oxide-functionalized brookite TiO2 nanorods [J].

Buonsanti, Raffaella ;

Snoeck, Etienne ;

Giannini, Cinzia ;

Gozzo, Fabia ;

Garcia-Hernandez, Mar ;

Angel Garcia, Miguel ;

Cingolani, Roberto ;

Cozzoli, Pantaleo Davide .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (19) :3680-3691

[4]

CHEN D, 2009, ADV MATER, V21, P1

[5] Development of macroporous Titania monoliths using a biocompatible method. Part 1: Material fabrication and characterization [J].

Chen, Yang ;

Yi, Yunyu ;

Brennan, John D. ;

Brook, Michael A. .

CHEMISTRY OF MATERIALS, 2006, 18 (22) :5326-5335

[6] Nanostructure engineering by templated self-assembly of block copolymers [J].

Cheng, JY ;

Mayes, AM ;

Ross, CA .

NATURE MATERIALS, 2004, 3 (11) :823-828

[7] Nonhydrolytic Route for Synthesis of ZnO and Its Use as a Recyclable Photocatalyst [J].

Das, Jaykrushna ;

Khushalani, Deepa .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (06) :2544-2550

[8] Protein-Mediated Layer-by-Layer Syntheses of Freestanding Microscale Titania Structures with Biologically Assembled 3-D Morphologies [J].

Fang, Yunnan ;

Wu, Qingzhong ;

Dickerson, Matthew B. ;

Cai, Ye ;

Shian, Samuel ;

Berrigan, John D. ;

Poulsen, Nicole ;

Kroeger, Nils ;

Sandhage, Kenneth H. .

CHEMISTRY OF MATERIALS, 2009, 21 (24) :5704-5710

[9] Nanoarchitecture of semiconductor titania nanosheets revealed by polarization-dependent total reflection fluorescence X-ray absorption fine structure [J].

Fukuda, K ;

Nakai, I ;

Oishi, C ;

Nomura, M ;

Harada, M ;

Ebina, Y ;

Sasaki, T .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (35) :13088-13092

[10] One-step synthesis of nano-micro chestnut TiO2 with rutile nanopins on the microanatase octahedron [J].

Hosono, Eiji ;

Fujihara, Shinobu ;

Lmai, Hiroaki ;

Honma, Itaru ;

Masaki, Ichihara ;

Zhou, Haoshen .

ACS NANO, 2007, 1 (04) :273-278

← 1 2 3 4 5 →