Poly(2-oxazoline)s based on fatty acids

被引：28
作者：
Hoogenboom, Richard [1 ]
机构：
[1] Univ Ghent, Dept Organ Chem, Supramol Chem Grp, B-9000 Ghent, Belgium
来源：
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY | 2011年 / 113卷 / 01期
关键词：
Cationic ring-opening polymerization; Fatty acid; Green chemistry; Living polymerization; Polymer; Renewable resources; RING-OPENING POLYMERIZATION; CYCLIC IMINO ETHERS; PENDANT PENTAMETHYLDISILOXANYL GROUPS; MICROWAVE-ASSISTED SYNTHESIS; IRON TRIS(BIPYRIDINE)-CENTERED POLYOXAZOLINES; FLUORESCENCE CORRELATION SPECTROSCOPY; CRITICAL SOLUTION TEMPERATURE; UNDECYL OXAZOLINE BLOCK; N-AROYL ETHYLENIMINES); AIR-WATER-INTERFACE;
D O I：
10.1002/ejlt.201000122
中图分类号：
TS2 [食品工业];
学科分类号：
0832 ;
摘要：
Poly(2-oxazoline)s are an interesting class of synthetic poly(amide) s that can be prepared by living cationic ring-opening polymerization. The properties of poly(2-oxazoline) s can be tuned by variation of the 2-substituent of the 2-oxazoline monomer. In this contribution the utilization of fatty acids as side chains for poly(2-oxazoline) s is highlighted. The incorporation of such long aliphatic side-chains results in hydrophobic crystalline poly(2-oxazoline) s that are often applied for the preparation of amphiphilic structures as well as for low surface energy and low adhesive coatings. The most popular fatty-acid based poly(2-oxazoline) s are the saturated poly(2-nonyl-2-oxazoline) and poly(2-undecyl-2-oxazoline) as well as the unsaturated poly(2-decenyl-2-oxazoline) and poly(2-"soy alkyl''-2-oxazoline).
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收藏
页码：59 / 71
页数：13
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