Corrosion behavior under accelerated SO2 corrosion tests of thin iron nitride films prepared by DIBS

被引:4
作者
Marco, J. F. [1 ]
Herranz, T. [1 ]
Gracia, M. [1 ]
Gancedo, J. R. [1 ]
Moutinho, F. [1 ,2 ]
Prieto, P. [3 ]
Sanz, J. M. [3 ]
机构
[1] CSIC, Inst Quim Fis Rocasolano, Madrid 28006, Spain
[2] Cent Univ Venezuela, Fac Ciencias, Dept Fis, Escuela Fis, Caracas 47586, Venezuela
[3] Univ Autonoma Madrid, Dept Fis Aplicada C 12, E-28049 Madrid, Spain
关键词
iron nitrides; corrosion; SO2; ICEMS; XPS; MOSSBAUER; COATINGS;
D O I
10.1002/sia.3250
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report on the corrosion behavior of thin films, prepared by dual ion beam sputtering ( DIBS), containing different concentrations of gamma'-and epsilon-iron nitride phases. When deposited on Si wafers, the film containing almost equal amounts of gamma'-Fe4N and epsilon-Fe3-xN phases shows the highest corrosion resistance. When deposited on iron substrates, all the films show almost total chemical degradation. We attribute this to the open microporosity of the different films deposited. Copyright (C) 2010 John Wiley & Sons, Ltd.
引用
收藏
页码:616 / 620
页数:5
相关论文
共 10 条
[1]   Corrosion resistance of titanium nitride and mixed titanium titanium nitride coatings on iron in humid SO2-containing atmospheres [J].
Agudelo, AC ;
Gancedo, JR ;
Marco, JF ;
Hanzel, D .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 1997, 15 (06) :3163-3169
[2]   Characterization of iron oxide thin films [J].
Aronniemi, M ;
Lahtinen, J ;
Hautojärvi, P .
SURFACE AND INTERFACE ANALYSIS, 2004, 36 (08) :1004-1006
[3]   Phase identification of iron nitrides and iron oxy-nitrides with Mossbauer spectroscopy [J].
Borsa, DM ;
Boerma, DO .
HYPERFINE INTERACTIONS, 2003, 151 (01) :31-48
[4]   Investigation of multiplet splitting of Fe 2p XPS spectra and bonding in iron compounds [J].
Grosvenor, AP ;
Kobe, BA ;
Biesinger, MC ;
McIntyre, NS .
SURFACE AND INTERFACE ANALYSIS, 2004, 36 (12) :1564-1574
[5]   Corrosion behaviour of AlN and TiAlN coatings on iron [J].
Marco, JF ;
Agudelo, AC ;
Gancedo, JR ;
Auger, MA ;
Sánchez, O ;
Albella, JM .
SURFACE AND INTERFACE ANALYSIS, 2006, 38 (04) :243-247
[6]   MOSSBAUER STUDY OF THE CORROSION BEHAVIOR OF PURE IRON AND WEATHERING STEEL UNDER A WET-DRY CYCLE [J].
MARCO, JF ;
DAVALOS, J ;
GANCEDO, JR ;
GRACIA, M .
HYPERFINE INTERACTIONS, 1989, 46 (1-4) :453-459
[7]   X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF IRON-OXIDES [J].
MCINTYRE, NS ;
ZETARUK, DG .
ANALYTICAL CHEMISTRY, 1977, 49 (11) :1521-1529
[8]   Microstructural, mechanical, and corrosion characterization of plasma-nitrided plastic injection mould steel [J].
Örtürk, O ;
Onmus, O ;
Williamson, DL .
SURFACE & COATINGS TECHNOLOGY, 2005, 196 (1-3) :341-348
[9]   Synthesis and characterization of iron nitrides. An XRD, Mossbauer, RBS and XPS characterization [J].
Prieto, P. ;
Marco, J. F. ;
Sanz, J. M. .
SURFACE AND INTERFACE ANALYSIS, 2008, 40 (3-4) :781-785
[10]   CHARACTERIZATION OF LASER-NITRIDED IRON AND SPUTTERED IRON NITRIDE FILMS [J].
SCHAAF, P ;
ILLGNER, C ;
NIEDERDRENK, M ;
LIEB, KP .
HYPERFINE INTERACTIONS, 1995, 95 (1-4) :199-225