Synthesis and crystal structure of Ca9Cu1.5(PO4)7 and reinvestigation of Ca9.5Cu(PO4)7

被引：35

作者：

Belik, AA ^{[1
]}

Yanov, OV ^{[1
]}

Lazoryak, BI ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

MATERIALS RESEARCH BULLETIN | 2001年 / 36卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

inorganic compounds; chemical synthesis; X-ray diffraction; crystal structure;

D O I：

10.1016/S0025-5408(01)00666-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Ca9Cu1.5(PO4)(7) was synthesized by the solid-state method at 1273 K followed by quenching in air. Crystal structure of Ca9Cu1.5(PO4)(7) was refined by the Rietveld method: space group R3c, a = 10.3379(1) Angstrom, c = 37.1898(3) Angstrom, Z = 6 with R-wp = 4.87%, R-p = 3.67%, S = 1.58, R-I = 2.42%, R-F = 1.07%. The structure of Ca9Cu1.5(PO4)(7) is isotypic with beta -Ca-3(PO4)(2) and Ca9.5Cu(PO4)(7). The M(5) site is fully occupied, and the M(4) site is half occupied by copper canons. The M(1)-M(3) sites are occupied by calcium canons. Copper canons in the M(4) site are displaced from the threefold axis due to long distances M(4)-O. Reinvestigation of crystal structure of Ca9.5Cu(PO4)(7) showed that the M(5) site is occupied by 0.79(1)Cu2+ + 0.21Ca(2+), and other copper canons locate in the M(4) site. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1863 / 1871

页数：9

共 50 条

[31] The new phosphates Ca(9)MLn(2/3)(PO4)(7) (M=Li, Na; Ln equals rare earth, Y, Bi)
Lazoryak, BI
Strunenkova, TV
Vovk, EA
Mikhailin, VV
Shpinkov, IN
Romanenko, AY
Schekoldin, VN
MATERIALS RESEARCH BULLETIN, 1996, 31 (06) : 665 - 671
[32] Crystal structure of silver strontium copper orthophosphate, AgSr4Cu4.5(PO4)6
Khmiyas, Jamal
Benhsina, Elhassan
Ouaatta, Said
Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 186 - +
[33] Whitlockite-related phosphates Sr9A(PO4)7 (A=Sc, Cr, Fe, Ga, and In):: Structure refinement of Sr9In(PO4)7 with synchrotron X-ray powder diffraction data
Belik, AA
Izumi, F
Ikeda, T
Okui, M
Malakho, AP
Morozov, VA
Lazoryak, BI
JOURNAL OF SOLID STATE CHEMISTRY, 2002, 168 (01) : 237 - 244
[34] Synthesis, structure, and physicochernical investigations of the new α Cu0.50TiO(PO4) oxyphosphate
Benmokhtar, S.
Belmal, H.
El Jazouli, A.
Chaminade, J. P.
Gravereau, P.
Pechev, S.
Grenier, J. C.
Villeneuve, G.
de Waal, D.
JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (02) : 772 - 779
[35] Crystal structure and vibrational properties of KMg4(PO4)3
Tomaszewski, PE
Maczka, M
Majchrowski, A
Waskowska, A
Hanuza, J
SOLID STATE SCIENCES, 2005, 7 (10) : 1201 - 1208
[36] The crystal structure of nacaphite, Na2Ca(PO4)F:: A re-investigation
Krivovichev, Sergey V.
Yakovenchuk, Victor N.
Ivanyuk, Gregory Yu.
Pakhomovsky, Yakov A.
Armbruster, Thomas
Selivanova, Ekaterina A.
CANADIAN MINERALOGIST, 2007, 45 (915-920) : 915 - 920
[37] Growth, Structure and Characterization of Solid Solution Ca9Y(VO4)7-x(PO4)x Single Crystals
Baumer, V. N.
Kosmyna, M. B.
Mateichenko, P. V.
Nazarenko, B. P.
Puzikov, V. M.
Ogorodnyk, I.
Slobodyamk, N.
Shekhovtsov, A. N.
Strutynska, N.
Zatovsky, I.
2014 IEEE INTERNATIONAL CONFERENCE ON OXIDE MATERIALS FOR ELECTRONIC ENGINEERING (OMEE), 2014, : 22 - 23
[38] Spectroscopic and Structural Properties of β-Tricalcium Phosphates Ca9RE(PO4)7 (RE = Nd, Gd, Dy)
Paterlini, Veronica
El Khouri, Asmaa
Bettinelli, Marco
Trucchi, Daniele Maria
Capitelli, Francesco
CRYSTALS, 2021, 11 (10)
[39] Synthesis and crystal structure of a barium-zinc-vanadyl-phosphate BaZn(VO)(PO4)(2) containing [(VO)PO4] layers
Meyer, S
MullerBuschbaum, H
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (03): : 367 - 371
[40] Novel laser crystals in Ca9Y(VO4)7-x(PO4)x mixed system
Kosmyna, M. B.
Mateychenko, P. V.
Nazarenko, B. P.
Shekhovtsov, A. N.
Aksenov, S. M.
Spassky, D. A.
Mosunov, A. V.
Stefanovich, S. Yu.
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 708 : 285 - 293

← 1 2 3 4 5 →