A microwave-assisted route for the solid-state synthesis of lead pyrophosphate, Pb2P2O7

被引：16

作者：

Guler, H ^{[1
]}

Kurtulus, F ^{[1
]}

机构：

[1] Balikesir Univ, Fac Sci, Dept Chem, TR-10100 Balikesir, Turkey

来源：

JOURNAL OF MATERIALS SCIENCE | 2005年 / 40卷 / 24期

关键词：

D O I：

10.1007/s10853-005-1809-y

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In this study, we have developed a new method based on microwave heating for the preparation of lead pyrophosphate compound, Pb2P2O7. The favoring of microwave heating as synthesis technique is based on the fact being much faster, cleaner and economical than conventional techniques. By following this new route, the lead pyrophosphate, Pb2P2O7, was obtained as a pure phase. The products were characterized by X-ray powder diffraction (XRD) and Fourier Transform IR (FTIR) spectroscopic techniques. Comparing the experimental XRD and FTIR data of the synthesized products with the reported literature data has revealed that there was mutually an excellent agreement. (c) 2005 Springer Science+ Business Media, Inc.

引用

页码：6565 / 6569

页数：5

共 15 条

[1]

[Anonymous], INFRARED SPECTRA INO

[2] Vibrational and 57Fe-Mossbauer spectra of some mixed cation diphosphates of the type MIIFe2III(P2O7)2 [J].

Baran, EJ ;

Mercader, RC ;

Massaferro, A ;

Kremer, E .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2004, 60 (05) :1001-1005

[3]

BRIXNER LH, 1973, J SOLID STATE CHEM, V6, P430, DOI [10.1016/0022-4596(73)90234-X, 10.1016/0022-4596(73)90170-9]

[4]

EYSEL W, 1973, J SOLID STATE CHEM, V6, P430

[5] CRYSTAL-STRUCTURES AND CRYSTAL-CHEMISTRY IN SYSTEM NA1+XZR2SIXP3-XO12 [J].

HONG, HYP .

MATERIALS RESEARCH BULLETIN, 1976, 11 (02) :173-182

[6] Fluoro-apatite and calcium phosphate nanoparticles by flame synthesis [J].

Loher, S ;

Stark, WJ ;

Maciejewski, M ;

Baiker, A ;

Pratsinis, SE ;

Reichardt, D ;

Maspero, F ;

Krumeich, F ;

Günther, D .

CHEMISTRY OF MATERIALS, 2005, 17 (01) :36-42

[7] PHOSPHATES AS CATALYSTS [J].

MOFFAT, JB .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1978, 18 (02) :199-258

[8] Mechanochemical effects on synthesis and properties of manganese-neodymium diphosphates [J].

Onoda, H ;

Sugino, N ;

Kojima, K ;

Nariai, H .

MATERIALS CHEMISTRY AND PHYSICS, 2003, 82 (03) :831-836

[9] Infrared and Raman spectra of Cs2VOP2O7 and single crystal Rb2(VO)3(P2O7)2 [J].

Pillai, VPM ;

Thomas, BR ;

Nayar, VU ;

Lii, KH .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1999, 55 (09) :1809-1817

[10]

RAMESH PD, 1994, J MATER RES, V12, P3057

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